JAMB 2025 Chemistry · Question 10
Mg + Pb → Mg + Pb What is the cell notation for the cell reaction above?
Options
- A.MgIPbIIMgIPb
- B.MgIMgIIPbIPb
- C.MgIMgIIPbIPb
- D.MgIMgIIPbIPb
Answer: C. MgIMgIIPbIPb
Explanation written with AI and checked against the answer key
Analyze the question: We need the correct cell notation (cell diagram) for the redox reaction Mg + Pb²⁺ → Mg²⁺ + Pb.
Concept: Cell notation is written as:
Anode (oxidation) electrode | anode ion || cathode ion | cathode electrode
- The single vertical line (|) shows a phase boundary (solid | solution).
- The double vertical line (||) shows the salt bridge.
- Oxidation (loss of electrons) occurs at the anode, written on the left.
- Reduction (gain of electrons) occurs at the cathode, written on the right.
Solution:
- Oxidation: Mg → Mg²⁺ + 2e⁻. Mg is oxidised, so it is the anode (left side): Mg | Mg²⁺
- Reduction: Pb²⁺ + 2e⁻ → Pb. Pb²⁺ is reduced, so it is the cathode (right side): Pb²⁺ | Pb
- Join them with the salt bridge: Mg | Mg²⁺ || Pb²⁺ | Pb
Checking the options:
- A: Electrode and ion are in the wrong places (Mg | Pb²⁺ is wrong). ✗
- B: The cathode half is written backwards (Pb | Pb²⁺), and the ion should come first on the right side. ✗
- C: Mg | Mg²⁺ || Pb²⁺ | Pb ✓
- D: Uses Mg⁺ and Pb⁺, which are the wrong charges. ✗
Tip: Remember "An Ox, Red Cat": Anode = Oxidation, Reduction = Cathode. Write the anode on the left and the cathode on the right, and read the notation as: metal | its ion || other ion | other metal. Also check that the ion charges match the equation.
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