JAMB 2025 Chemistry · Question 11

Alkenes are represented with the general molecular formula

Options

  1. A.Cn_nH2n_{2n}
  2. B.Cn_nH2n−2_{2n-2}
  3. C.Cn_nH2n+2_{2n+2}
  4. D.Cn_nH2n+1_{2n+1}OH

Answer: A. Cn_nH2n_{2n}

Explanation written with AI and checked against the answer key

Analysis

The question asks for the general molecular formula of alkenes, which are a class of hydrocarbons characterized by the presence of at least one carbon-carbon double bond (C=CC=C).

Concept Explanation

In organic chemistry, hydrocarbons are classified based on the type of bonds between their carbon atoms:

  1. Alkanes: These are saturated hydrocarbons containing only single bonds. Their general formula is CnH2n+2C_nH_{2n+2}.
  2. Alkenes: These are unsaturated hydrocarbons containing at least one double bond. Because a double bond "uses up" two hydrogen atoms that would otherwise be attached to the carbons, the formula is reduced by two hydrogens compared to alkanes. The general formula is CnH2nC_nH_{2n}.
  3. Alkynes: These are unsaturated hydrocarbons containing at least one triple bond. Their general formula is CnH2n−2C_nH_{2n-2}.
  4. Alkanols (Alcohols): These are organic compounds containing a hydroxyl (-OH) group. Their general formula is CnH2n+1OHC_nH_{2n+1}OH.
Step-by-Step Solution
  • Step 1: Identify the homologous series. We are looking for Alkenes.
  • Step 2: Recall the degree of unsaturation. Alkenes have one double bond, which removes two hydrogen atoms from the corresponding alkane (CnH2n+2−2H=CnH2nC_nH_{2n+2} - 2H = C_nH_{2n}).
  • Step 3: Compare with the given options: • A: CnH2nC_nH_{2n} (Matches the alkene formula) • B: CnH2n−2C_nH_{2n-2} (This is the formula for Alkynes) • C: CnH2n+2C_nH_{2n+2} (This is the formula for Alkanes) • D: CnH2n+1OHC_nH_{2n+1}OH (This is the formula for Alkanols)
Conclusion

The general molecular formula for alkenes is CnH2nC_nH_{2n}.

Exam Tip

To remember these easily, think of the hydrogen count:

  • Alkanes (Single bond): 2n+22n + 2 (The "plus" gives you more)
  • Alkenes (Double bond): 2n2n (The "middle" ground)
  • Alkynes (Triple bond): 2n−22n - 2 (The "minus" takes away)

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