WAEC 2021 Chemistry · Question 12

Which of the following statements is correct about ionization energy? It

Options

  1. A.decreases across the periods
  2. B.results in the formation of an anion
  3. C.causes Metalic nuclei to disintegrate
  4. D.decreases down the group

Answer: D. decreases down the group

Explanation written with AI and checked against the answer key

Analyze the question: We need the correct statement about ionization energy, which is the energy required to remove one mole of electrons from one mole of gaseous atoms, forming a positive ion (cation).

Concept: Ionization energy trends in the Periodic Table:

  • Across a period (left to right): it generally increases, because nuclear charge increases while the electrons are added to the same shell. The nucleus holds the outer electrons more tightly and atomic radius decreases.
  • Down a group: it decreases, because atomic radius increases, there are more inner shells shielding the outer electron, and the outer electron is held less tightly and is easier to remove.

Evaluating each option:

  • A. Decreases across the periods: Wrong. It generally increases across a period.
  • B. Results in the formation of an anion: Wrong. Losing electrons forms a cation (positive ion). Gaining electrons forms an anion.
  • C. Causes metallic nuclei to disintegrate: Wrong. Ionization removes outer electrons only, and the nucleus is unaffected. Nuclear disintegration is radioactivity.
  • D. Decreases down the group: Correct. For example, in Group 1: Li (520 kJ/mol) > Na (496) > K (419), so the energy needed falls as you go down.

Tip: Remember "Across → Up, Down → Down" for ionization energy: it goes up across a period and down a group. Also remember that ionization makes a cation (think "caTion = posiTive"), so you can eliminate option B quickly.

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