WAEC 2021 Chemistry · Question 11

The following ions have the same electron configuration except  8_{8}O, 12_{12}Mg, 13_{13}AI, 17_{17}CI

Options

  1. A.CI−^{-}
  2. B.O2−^{2-}
  3. C.Mg2+^{2+}
  4. D.AI3+^{3+}

Answer: A. CI−^{-}

Explanation written with AI and checked against the answer key

Analyze the question: We need to find the ion whose electron configuration is different from the others. Atoms form ions by gaining or losing electrons, so we count the electrons in each ion.

Concept: Ions with the same number of electrons are isoelectronic, so they have the same electron configuration.

Solution:

  • Cl⁻: Z = 17, gains 1 electron, so 18 electrons: 2, 8, 8 (1s² 2s² 2p⁶ 3s² 3p⁶)
  • O²⁻: Z = 8, gains 2 electrons, so 10 electrons: 2, 8 (1s² 2s² 2p⁶)
  • Mg²⁺: Z = 12, loses 2 electrons, so 10 electrons: 2, 8
  • Al³⁺: Z = 13, loses 3 electrons, so 10 electrons: 2, 8

O²⁻, Mg²⁺ and Al³⁺ all have 10 electrons, the same configuration as neon (1s² 2s² 2p⁶). Cl⁻ has 18 electrons, the same configuration as argon, so it is the odd one out.

Answer: A. Cl⁻.

Tip: For "same electron configuration" questions, always calculate the electron count: protons ± charge. Remember that anions come from Period 2 and 3 nonmetals gaining electrons, and metal cations lose electrons to reach the noble gas configuration of the preceding period (Ne for O²⁻, Mg²⁺, Al³⁺, and Ar for Cl⁻).

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