WAEC 2012 Chemistry · Question 38

A substance L reacts with NH4_4NO3(aq)_{3(aq)} to generate ammonia gas. L is likely to be

Options

  1. A.HCl
  2. B.NaOH
  3. C.CH3COOH
  4. D.CaSO4

Answer: B. NaOH

Explanation written with AI and checked against the answer key

Analyze the question: Ammonium nitrate (NH₄NO₃) is an ammonium salt. We need a substance that reacts with it to release ammonia gas (NH₃).

Concept: Ammonium salts react with alkalis (strong bases) to liberate ammonia gas. This is the standard laboratory test for the ammonium ion (NH₄⁺):

NH₄⁺ + OH⁻ → NH₃ + H₂O

The reaction is usually warmed gently, and the ammonia is recognised by its pungent smell and its ability to turn damp red litmus paper blue.

Solution:

  • A. HCl: an acid. It cannot remove H⁺ from NH₄⁺, so there is no reaction and no ammonia.
  • B. NaOH: a strong base. It supplies OH⁻, which takes H⁺ from NH₄⁺ and releases NH₃:

NH₄NO₃ + NaOH → NaNO₃ + H₂O + NH₃↑

  • C. CH₃COOH: a weak acid, so no ammonia is formed.
  • D. CaSO₄: a neutral salt. It is not basic, so it does not liberate ammonia.

Answer: The substance L is NaOH, which is option B.

Tip: Remember "Ammonium salt + alkali → ammonia gas". Whenever a question asks what releases ammonia from an ammonium salt, look for the base or alkali (NaOH, KOH, Ca(OH)₂) and ignore the acids and neutral salts.

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