WAEC (WASSCE) 2012

2012 WAEC (WASSCE) Chemistry Past Questions

The 2012 WAEC (WASSCE) Chemistry past questions with answers: 44 objective questions from the 2012 paper in the DeeepSolve question bank, each with its answer behind "Show answer". Try each question before you check, then practise the paper as a timed WAEC-style CBT.

Past questions © the examination body (JAMB/WAEC/NECO). DeeepSolve is not affiliated with them. Rights holders: see /copyright.

Questions

  1. 1.

    Which of the following halogens is liquid at room temperature?

    1. A.Chlorine
    2. B.Fluorine
    3. C.lodine
    4. D.Bromine
    Show answer

    Answer: D. Bromine

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  2. 2.

    Which of the following devices function on redox reaction? l. Dry cell ll. Car battery III. Electric generator

    1. A.l and lll only
    2. B.ll and lll only
    3. C.l and ll only
    4. D.l, ll and lll
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    Answer: C. l and ll only

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  3. 3.

    At ordinary temperature H2_2O is a liquid while H2_2S is a gas. This is because H2_2O has

    1. A.weak intermolecular forces holding its molecules together
    2. B.strong hydrogen bonds holding its molecules together
    3. C.induced dipole-induced dipole forces between its molecules
    4. D.ionic force between its molecules
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    Answer: B. strong hydrogen bonds holding its molecules together

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  4. 4.

    The d-block elements are paramagnetic because they

    1. A.contain paired electrons which are repelled by magnetic field
    2. B.contain unpaired electrons in the partially filled 3d-orbital
    3. C.contain paired electrons which are repelled by magnetic field force
    4. D.have delocalized valence electrons
    Show answer

    Answer: B. contain unpaired electrons in the partially filled 3d-orbital

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  5. 5.

    A metal M forms two types of chlorine, MCl2_2 and MCl3_3 which of the following laws best explains the relationship between the chlorides? Law of

    1. A.conservation of mass
    2. B.definite proportion
    3. C.multiple proportion
    4. D.reciprocal proportion
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    Answer: C. multiple proportion

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  6. 6.

    MgO does not readily dissolve in water because

    1. A.of its high melting point
    2. B.it is a covalent compound
    3. C.it forms a hydroxide when dissolved in water
    4. D.its lattice energy is higher than its hydration energy
    Show answer

    Answer: D. its lattice energy is higher than its hydration energy

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  7. 7.

    Consider the reaction represented by the following equation: CuO(s)_{(s)} + H2_2SO4(aq)_{4(aq)} → CuSO4(aq)_{4(aq)} + H2_2O(l)_{(l)}. Which of the following factors will not affect the rate of the reaction?

    1. A.Particle size of CuO(s)
    2. B.Concentration of H2SO4(aq)
    3. C.Temperature of the reacting mixture
    4. D.Pressure of reaction system
    Show answer

    Answer: D. Pressure of reaction system

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  8. 8.

    The postulate that molecules are in constant random motion best explains why liquids

    1. A.can undergo solidification
    2. B.maintain their volumes
    3. C.are incompressible
    4. D.have no characteristic shape
    Show answer

    Answer: D. have no characteristic shape

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  9. 9.

    Which of the following ions has an electron configuration different from the other?

    1. A.17CI-
    2. B.8O2-
    3. C.12Mg2+
    4. D.13AI3+
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    Answer: A. 17CI-

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  10. 10.

    Which of the following industrial processes depends on the action of enzymes?

    1. A.Liquefaction of air
    2. B.Manufacture of soap
    3. C.Brewing of beer
    4. D.Catalytic cracking
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    Answer: C. Brewing of beer

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  11. 11.

    The shape of a graphite crystal is

    1. A.tetrahedral
    2. B.pyramidal
    3. C.hexagonal
    4. D.octahedral
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    Answer: C. hexagonal

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  12. 12.

    Which of the following statements about a radioactive substance is/are correct? l. lt emits radiation continuously and spontaneously. ll. The emitted radiations are affected by temperature and pressure III. The radiation can penetrate opaque matter

    1. A.ll only
    2. B.l and ll only
    3. C.l and lll only
    4. D.ll and lll only
    Show answer

    Answer: C. l and lll only

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  13. 13.

    A sample of a gas may be identified as chlorine if it turns

    1. A.damp blue litmus paper red
    2. B.lime water miky
    3. C.lead ethanoate paper black
    4. D.starch iodide paper blue-black
    Show answer

    Answer: D. starch iodide paper blue-black

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  14. 14.

    Which of the following electron configurations represents that of an atom in its ground state?

    1. A.1s 22s12p1
    2. B.1s22s22p63s13p1
    3. C.1s22s12p3
    4. D.1s22s22p63s0
    Show answer

    Answer: D. 1s22s22p63s0

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  15. 15.

    The oxidation number of Fe in [Fe(CN)6_6]3−^{3-} is

    1. A.+3
    2. B.+2
    3. C.-2
    4. D.-3
    Show answer

    Answer: A. +3

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  16. 16.

    A metal that is widely used in the manufacture of paints and overhead electric cables is

    1. A.aluminium
    2. B.copper
    3. C.iron
    4. D.lead
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    Answer: A. aluminium

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  17. 17.

    A tertiary alkanol has a molecular formula C4_4H10_{10}O. What is the structural formula of the compound?

    1. A.(CH 3)2CHCH2OH
    2. B.CH3CH2CH(OH)CH3
    3. C.(CH3)3COH
    4. D.CH3CH2CH2CH2OH
    Show answer

    Answer: C. (CH3)3COH

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  18. 18.

    Consider the reaction represented by the following equation: xCH3_3OH + yO2_2 → 2CO2_2 + zH2_2O. The values of x,y and z respectively, are

    1. A.2,3 and 4
    2. B.2, 4 and 3
    3. C.1,2 and 3
    4. D.1, 3 and 5
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    Answer: A. 2,3 and 4

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  19. 19.

    Two elements, X and Y are in the same group on the periodic table because they both have the same

    1. A.number of electronic shells
    2. B.number of valence electrons
    3. C.atomic size
    4. D.atomic number
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    Answer: B. number of valence electrons

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  20. 20.

    Consider the following reaction equation: C16_{16}H34_{34} → C5_5H12_{12} + C11_{11}H22_{22}. The process represented by the equation is

    1. A.cracking
    2. B.fermentation
    3. C.polymerization
    4. D.reforming
    Show answer

    Answer: A. cracking

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  21. 21.

    Brass is a mixture of

    1. A.Cu and Sn
    2. B.Cu and Zn
    3. C.Cu and Mg
    4. D.Cu and Pb
    Show answer

    Answer: B. Cu and Zn

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  22. 22.

    Which of the following metals would readily displace hydrogen from steam?

    1. A.Copper
    2. B.Lead
    3. C.Magnesium
    4. D.Silver
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    Answer: C. Magnesium

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  23. 23.

    Which of the following substances is mainly responsible for the depletion of the ozone layer?

    1. A.Oxgyen
    2. B.Chlorofluorocarbon
    3. C.Carbon (ll) oxide
    4. D.Nitrogen (ll) oxide
    Show answer

    Answer: B. Chlorofluorocarbon

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  24. 24.

    When a substance changes directly from the solid state to the gaseous state without forming a liquid, the substance is said to

    1. A.condense
    2. B.evaporate
    3. C.sublime
    4. D.precipitate
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    Answer: C. sublime

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  25. 25.

    Which of the following gases has the lowest rate of diffusion under the same condition? [H = 1.00; He = 4. 00; O = 16.0; CI = 35.5]

    1. A.CI2
    2. B.H2
    3. C.He
    4. D.O2
    Show answer

    Answer: A. CI2

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  26. 26.

    The vapour pressure of a liquid depends on l. temperature. ll. rate of condensation. III. cohesive forces holding the particles together

    1. A.l only
    2. B.l and ll only
    3. C.l and lll only
    4. D.ll and lll only
    Show answer

    Answer: C. l and lll only

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  27. 27.

    Consider the following reaction equation: CaCO3(s)_{3(s)} + 2HCI(aq)_{(aq)} → CaCl2(aq)_{2(aq)} + H2_2O(l)_{(l)} + CO2(g)_{2(g)}. What mass of CaCI2_2 would be obtained when 25.0g of CaCO3(s)_{3(s)} is reacted with excess HCI(aq)_{(aq)}? [CaCO3=100;CaCI_3 = 100; CaCI_2$ = 111]

    1. A.4.00g
    2. B.4.44 g
    3. C.18.9 g
    4. D.27.8 g
    Show answer

    Answer: D. 27.8 g

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  28. 28.

    The number of sulphur atoms in 3.20g of SO2(g)_{2(g)} is [O = 16.0;S = 32.0; Avogadro constant = 6.02 x 1023^{23}]

    1. A.3.01 x 1022
    2. B.6.02 x 1022
    3. C.6.02 x1023
    4. D.1.20 x 1024
    Show answer

    Answer: A. 3.01 x 1022

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  29. 29.

    Which of the following pH values indicates that a solution is a strong base?

    1. A.1
    2. B.5
    3. C.9
    4. D.13
    Show answer

    Answer: D. 13

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  30. 30.

    The volume occupied by 0.4 g of hydrogen gas at s.t.p. is [H = 1. 00; Molar volume at s.t.p. = 22.4 dm3]

    1. A.2.24 dm3
    2. B.4.48dm3
    3. C.22.4dm3
    4. D.44.8dm 3
    Show answer

    Answer: B. 4.48dm3

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  31. 31.

    The number of orbitals in a p-sub level of an atom is

    1. A.2
    2. B.3
    3. C.5
    4. D.6
    Show answer

    Answer: B. 3

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  32. 32.

    The complex compound formed when aluminum dissolves in aqueous sodium hydroxide is

    1. A.Na3Al(OH)4.
    2. B.NaAl(OH)4
    3. C.NaAl(OH)3
    4. D.Na2Al(OH)3
    Show answer

    Answer: B. NaAl(OH)4

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  33. 33.

    On heating, the following trioxocarbonate (IV) salts decompose to give solid residue except

    1. A.ammonium trioxocarbonate (IV)
    2. B.calcium trioxocarbonate (IV)
    3. C.lead (ll) trioxocarbonate(IV)
    4. D.zinc trioxocarbonate (IV)
    Show answer

    Answer: A. ammonium trioxocarbonate (IV)

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  34. 34.

    The atomic radii of metals are usually

    1. A.greater than their ionic radii
    2. B.equal to their ionic radii
    3. C.less than their ionic radii
    4. D.less than those of non-metals in the same period
    Show answer

    Answer: A. greater than their ionic radii

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  35. 35.

    A spot of oil paint on a shirt can best be removed using?

    1. A.brine
    2. B.detergent
    3. C.kerosine
    4. D.warm water
    Show answer

    Answer: C. kerosine

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  36. 36.

    The hydrolysis of NH4_4CI gives

    1. A.an acidic solution
    2. B.an alkaline solution
    3. C.a buffer solution
    4. D.a neutral solution
    Show answer

    Answer: A. an acidic solution

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  37. 37.

    The complex compound formed by the combination of two elements with a large electronegativity difference is likely to be

    1. A.polar covalent
    2. B.giant molecular
    3. C.covalent
    4. D.ionic
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    Answer: D. ionic

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  38. 38.

    A substance L reacts with NH4_4NO3(aq)_{3(aq)} to generate ammonia gas. L is likely to be

    1. A.HCl
    2. B.NaOH
    3. C.CH3COOH
    4. D.CaSO4
    Show answer

    Answer: B. NaOH

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  39. 39.

    The formula of mercury (l) dioxonitrate (III) is

    1. A.HgNO3
    2. B.Hg2NO2
    3. C.Hg2(NO2)2
    4. D.Hg(NO3)2
    Show answer

    Answer: C. Hg2(NO2)2

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  40. 40.

    Which of the following substances would not produce ethanol when fermented?

    1. A.Cane sugar
    2. B.Glucose
    3. C.Starch
    4. D.Vinegar
    Show answer

    Answer: D. Vinegar

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  41. 41.

    An alkanol can be prepared by the reaction of an alkene with

    1. A.concentrated tetraoxosulphate (VI) acid
    2. B.bromine tetrachloroethane
    3. C.aqueous potassium tetraoxomanganate (VII)
    4. D.sodium hydroxide solution
    Show answer

    Answer: A. concentrated tetraoxosulphate (VI) acid

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  42. 42.

    The energy evolved when magnesium burns in air is in the form of

    1. A.heat
    2. B.heat and sound
    3. C.light and heat
    4. D.sound
    Show answer

    Answer: C. light and heat

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  43. 43.

    Which of the following elements is a metalloid?

    1. A.Carbon
    2. B.Oxygen
    3. C.Silicon
    4. D.Sodium
    Show answer

    Answer: C. Silicon

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  44. 44.

    Which of the following pollutants is not usually recycled?

    1. A.Aluminium cans
    2. B.Glass bottles
    3. C.Nuclear wastes
    4. D.Paper wastes
    Show answer

    Answer: C. Nuclear wastes

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