JAMB 2025 Chemistry · Question 42

The compound in which the oxidation state of nitrogen is + 3 is

Options

  1. A.N2_2O5_5
  2. B.N2_2O3_3
  3. C.N2_2O4_4
  4. D.N2_2O

Answer: B. N2_2O3_3

Explanation written with AI and checked against the answer key

To find the oxidation state of nitrogen in these compounds, we use the rule that the sum of oxidation states in a neutral compound is zero, and the oxidation state of oxygen is typically -2.

Step-by-Step Analysis

Let the oxidation state of nitrogen be xx.

A. N2_2O5_5 2(x)+5(−2)=02(x) + 5(-2) = 0 2x−10=02x - 10 = 0 2x=102x = 10 x=+5x = +5

B. N2_2O3_3 2(x)+3(−2)=02(x) + 3(-2) = 0 2x−6=02x - 6 = 0 2x=62x = 6 x=+3x = +3

C. N2_2O4_4 2(x)+4(−2)=02(x) + 4(-2) = 0 2x−8=02x - 8 = 0 2x=82x = 8 x=+4x = +4

D. N2_2O 2(x)+1(−2)=02(x) + 1(-2) = 0 2x−2=02x - 2 = 0 2x=22x = 2 x=+1x = +1

Conclusion

Comparing our results, the compound where nitrogen has an oxidation state of +3 is N2_2O3_3.

Exam Tip

When calculating oxidation states for oxides of nitrogen, remember that nitrogen can exhibit multiple oxidation states (+1 to +5). A quick trick is to look at the subscript of the oxygen: in N2OyN_2O_y, the oxidation state of nitrogen is simply +y+y. For example, in N2O3N_2O_3, y=3y=3, so the state is +3+3. This works perfectly for these specific nitrogen oxides!

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