JAMB 2024 Chemistry · Question 124
The shape of the molecule of Carbon(IV) oxide is
Options
- A.tetrahedral
- B.pyramidal
- C.plannar
- D.linear
Answer: D. linear
Explanation written with AI and checked against the answer key
1. Analyze the question
The question asks for the geometric shape of the Carbon(IV) oxide () molecule. To determine this, we need to look at the bonding arrangement around the central carbon atom.
2. Explain the concept
The shape of a molecule is determined by the Valence Shell Electron Pair Repulsion (VSEPR) theory. This theory states that electron pairs around a central atom will arrange themselves as far apart as possible to minimize repulsion.
- Step 1: Draw the Lewis structure. Carbon is in Group 4, so it has 4 valence electrons. Oxygen is in Group 6, so it has 6 valence electrons. In , the carbon atom forms a double bond with each of the two oxygen atoms ().
- Step 2: Count the electron domains. Around the central carbon atom, there are two double bonds. In VSEPR theory, double bonds are treated as a single "domain" or region of electron density.
- Step 3: Determine the geometry. With two electron domains around the central atom and no lone pairs on the carbon, the electron pairs push each other to opposite sides to achieve a bond angle of 180°. This results in a straight-line geometry.
3. Show the solution
- Central Atom: Carbon (C)
- Bonding: Two double bonds to Oxygen ()
- Lone Pairs on Carbon: 0
- Arrangement: The two double bonds repel each other equally, forcing the molecule into a straight line.
- Bond Angle: 180°
Since there are no lone pairs on the central carbon to distort the shape, the molecule remains perfectly straight.
4. Identify the answer
Comparing our findings to the options: A. Tetrahedral (e.g., ) B. Pyramidal (e.g., ) C. Planar (e.g., ) D. Linear (e.g., )
The correct shape is linear.
5. Tip
Memory Trick: Think of "Linear" as a straight line. Any molecule with a central atom bonded to only two other atoms and no lone pairs (like , , or ) will always be linear with a 180° bond angle.
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