JAMB 2024 Chemistry · Question 124

The shape of the molecule of Carbon(IV) oxide is

Options

  1. A.tetrahedral
  2. B.pyramidal
  3. C.plannar
  4. D.linear

Answer: D. linear

Explanation written with AI and checked against the answer key

1. Analyze the question

The question asks for the geometric shape of the Carbon(IV) oxide (CO2CO_2) molecule. To determine this, we need to look at the bonding arrangement around the central carbon atom.

2. Explain the concept

The shape of a molecule is determined by the Valence Shell Electron Pair Repulsion (VSEPR) theory. This theory states that electron pairs around a central atom will arrange themselves as far apart as possible to minimize repulsion.

  • Step 1: Draw the Lewis structure. Carbon is in Group 4, so it has 4 valence electrons. Oxygen is in Group 6, so it has 6 valence electrons. In CO2CO_2, the carbon atom forms a double bond with each of the two oxygen atoms (O=C=OO=C=O).
  • Step 2: Count the electron domains. Around the central carbon atom, there are two double bonds. In VSEPR theory, double bonds are treated as a single "domain" or region of electron density.
  • Step 3: Determine the geometry. With two electron domains around the central atom and no lone pairs on the carbon, the electron pairs push each other to opposite sides to achieve a bond angle of 180°. This results in a straight-line geometry.
3. Show the solution
  • Central Atom: Carbon (C)
  • Bonding: Two double bonds to Oxygen (O=C=OO=C=O)
  • Lone Pairs on Carbon: 0
  • Arrangement: The two double bonds repel each other equally, forcing the molecule into a straight line.
  • Bond Angle: 180°

Since there are no lone pairs on the central carbon to distort the shape, the molecule remains perfectly straight.

4. Identify the answer

Comparing our findings to the options: A. Tetrahedral (e.g., CH4CH_4) B. Pyramidal (e.g., NH3NH_3) C. Planar (e.g., BF3BF_3) D. Linear (e.g., CO2CO_2)

The correct shape is linear.

5. Tip

Memory Trick: Think of "Linear" as a straight line. Any molecule with a central atom bonded to only two other atoms and no lone pairs (like CO2CO_2, BeCl2BeCl_2, or CS2CS_2) will always be linear with a 180° bond angle.

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