JAMB 2024 Chemistry · Question 123
An organic compound with general formula RCOR' is an
Options
- A.alkanone
- B.alkanal
- C.alkanoate
- D.alkanoic acid
Answer: A. alkanone
Explanation written with AI and checked against the answer key
Step 1: Analyze the question We need to identify the homologous series from the general formula RCOR'. Here R and R' are both alkyl groups (or hydrocarbon groups) attached to a carbonyl carbon (C=O).
Step 2: Recall the functional groups
| Class | General formula | Functional group | |---|---|---| | Alkanal (aldehyde) | RCHO | carbonyl with one H attached | | Alkanone (ketone) | RCOR' | carbonyl between two carbon groups | | Alkanoic acid | RCOOH | carboxyl group | | Alkanoate (ester) | RCOOR' | carboxyl with an alkyl group in place of H |
Step 3: Match the formula RCOR' has a carbonyl group (C=O) bonded to two hydrocarbon groups, R and R'. That is the structure of a ketone, named alkanone in IUPAC nomenclature.
- It is not an alkanal, because an aldehyde has at least one H on the carbonyl carbon (RCHO).
- It is not an alkanoate, because an ester has an extra oxygen (RCOOR').
- It is not an alkanoic acid, because an acid has the -COOH group.
Example: CH₃COCH₃ is propanone (acetone), the simplest ketone.
Answer: A. alkanone
Exam tip: Look at what is attached to the C=O.
- H and R gives aldehyde (alkanal).
- R and R' gives ketone (alkanone).
- OH gives acid.
- OR' gives ester (alkanoate).
Notice that the "COO" in an ester formula has two oxygens. RCOR' has only one oxygen, so it must be a ketone.
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