JAMB 2019 Chemistry · Question 37

Elements X and Y have electronic configurations 1s ^2 2s ^2 2p ^4 and 1s ^2 2s ^2 2p ^6 3s ^2 3p ^1…

Question

Elements X and Y have electronic configurations 1s2^22s2^22p4^4 and 1s2^22s2^22p6^63s2^23p1^1 respectively. When they combine, the formula of the compound formed is

  1. A.XY
  2. B.X2_2Y
  3. C.Y2_2X3_3
  4. D.X2_2Y3_3

Answer: C. Y2_2X3_3

Explanation written with AI and checked against the answer key

1. Analyze the Question

We are given the electronic configurations of two elements, X and Y. We need to determine their valencies (combining powers) based on their valence electrons to find the chemical formula of the compound they form.

2. Explain the Concept
  • Element X: The configuration is 1s22s22p41s^2 2s^2 2p^4. The outermost shell is the second shell (n=2n=2), which contains 2+4=62 + 4 = 6 electrons. To achieve a stable octet (8 electrons), it needs to gain 2 electrons. Therefore, its valency is -2.
  • Element Y: The configuration is 1s22s22p63s23p11s^2 2s^2 2p^6 3s^2 3p^1. The outermost shell is the third shell (n=3n=3), which contains 2+1=32 + 1 = 3 electrons. To achieve stability, it will lose these 3 electrons. Therefore, its valency is +3.
3. Show the Solution

To find the formula of the compound, we use the "criss-cross" method:

  1. Identify the charges (valencies): • X has a charge of -2 (it acts as an anion). • Y has a charge of +3 (it acts as a cation).
  1. Write the symbols with their charges: • Y3+Y^{3+} and X2−X^{2-}
  1. Criss-cross the charges to become subscripts: • The charge of Y (3) becomes the subscript of X. • The charge of X (2) becomes the subscript of Y.
  1. Resulting formula: • Y2X3Y_2X_3
4. Identify the Answer

Comparing our result (Y2X3Y_2X_3) with the given options: A. XY B. X2_2Y C. Y2_2X3_3 D. X2_2Y3_3

The correct option is C.

5. Exam Tip

When determining the formula of a compound, remember the "Octet Rule": Elements with 1, 2, or 3 valence electrons generally lose them to form positive ions (cations), while elements with 5, 6, or 7 valence electrons generally gain electrons to form negative ions (anions). Always write the metal (cation) first, followed by the non-metal (anion).

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