JAMB 2017 Chemistry · Question 16

The oxidation number of iodine in KIO3 is

Options

  1. A.+7
  2. B.+3
  3. C.+5
  4. D.+6

Answer: C. +5

Explanation written with AI and checked against the answer key

Analysis

To find the oxidation number of iodine (I) in potassium iodate (KIO3KIO_3), we use the rules of oxidation states. The sum of the oxidation numbers of all atoms in a neutral compound must equal zero.

Concept
  • Potassium (K): As a Group 1 element, it always has an oxidation number of +1.
  • Oxygen (O): In most compounds (like this one), it has an oxidation number of -2.
  • Iodine (I): This is the unknown element we need to solve for. Let's represent it as xx.
Step-by-Step Solution
  1. Set up the equation: The sum of the oxidation numbers in KIO3KIO_3 is: (K)+(I)+3(O)=0(K) + (I) + 3(O) = 0
  1. Substitute the known values: (+1)+(x)+3(−2)=0(+1) + (x) + 3(-2) = 0
  1. Simplify the equation: 1+x−6=01 + x - 6 = 0 x−5=0x - 5 = 0
  1. Solve for xx: x=+5x = +5

The oxidation number of iodine in KIO3KIO_3 is +5.

Conclusion

Comparing our result with the given options: A. +7 B. +3 C. +5 D. +6

The correct option is C.

Exam Tip

When calculating oxidation numbers, always remember that the sum of oxidation states for a neutral molecule is 0, but if you are dealing with a polyatomic ion (like SO42−SO_4^{2-}), the sum must equal the charge of the ion (in this case, -2). This is a common trap in JAMB Chemistry!

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