JAMB 2015 Chemistry · Question 45

Chlorine gas turns damp starch-iodide paper

Options

  1. A.pink
  2. B.colourless
  3. C.red
  4. D.dark blue

Answer: D. dark blue

Explanation written with AI and checked against the answer key

1. Analyze the question

The question asks for the observable change that occurs when chlorine gas comes into contact with damp starch-iodide paper. This is a classic test for oxidizing agents in chemistry.

2. Explain the concept

Chlorine (Cl2Cl_2) is a powerful oxidizing agent. Starch-iodide paper contains potassium iodide (KIKI) and starch. When an oxidizing agent like chlorine gas is introduced, it reacts with the iodide ions (I−I^-) in the paper to produce free iodine (I2I_2).

The chemical equation for this reaction is: Cl2(g)+2I(aq)−→2Cl(aq)−+I2(s)Cl_{2(g)} + 2I^-_{(aq)} \rightarrow 2Cl^-_{(aq)} + I_{2(s)}

Once the free iodine is produced, it reacts with the starch present in the paper to form a deep blue-black complex. This reaction is a standard qualitative test used to detect the presence of oxidizing gases.

3. Show the solution
  • Step 1: Chlorine gas acts as an oxidizing agent.
  • Step 2: It displaces iodine from the potassium iodide in the damp paper.
  • Step 3: The liberated iodine reacts with the starch molecules.
  • Step 4: The starch-iodine complex creates a characteristic dark blue (or blue-black) color.
4. Identify the answer

Comparing our findings to the provided options: A. pink B. colourless C. red D. dark blue

The reaction produces a dark blue color. This matches option D.

5. Tip

Think of this as a "color-coded" test: Iodine + Starch = Blue-Black. Whenever you see "starch-iodide" in a question, immediately associate it with the detection of an oxidizing agent and the resulting dark blue color. This is a very common question in JAMB Chemistry, so keep it in your memory bank!

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