JAMB 2014 Chemistry · Question 40

H2O(g)+C(s)→H2(g)+CO(g)H_2O_{(g)} + C_{(s)} → H_{2(g)} + CO_{(g)} The oxidizing agent in the reaction above is

Options

  1. A.CO(g)
  2. B.C(s)
  3. C.H2O(g)
  4. D.H(2)(g)

Answer: C. H2O(g)

Explanation written with AI and checked against the answer key

Analysis of the Question

The question asks us to identify the oxidizing agent in the chemical reaction: H2O(g)+C(s)→H2(g)+CO(g)H_2O_{(g)} + C_{(s)} \rightarrow H_{2(g)} + CO_{(g)}

Explaining the Concept

To identify the oxidizing agent, we must track the changes in the oxidation states of the elements involved:

  1. Oxidation: This is the gain of oxygen, loss of hydrogen, or an increase in oxidation number. The substance that undergoes oxidation is called the reducing agent.
  2. Reduction: This is the loss of oxygen, gain of hydrogen, or a decrease in oxidation number. The substance that undergoes reduction is called the oxidizing agent.

Assigning Oxidation Numbers:

  • In H2OH_2O: Hydrogen is +1+1, Oxygen is −2-2.
  • In CC (elemental state): Oxidation number is 00.
  • In H2H_2 (elemental state): Oxidation number is 00.
  • In COCO: Carbon is +2+2, Oxygen is −2-2.
Step-by-Step Solution
  1. Track Carbon (CC): Carbon goes from 00 (in C(s)C_{(s)}) to +2+2 (in CO(g)CO_{(g)}). Since its oxidation number increased, Carbon is oxidized. Therefore, Carbon acts as the reducing agent.
  2. Track Hydrogen (HH): Hydrogen goes from +1+1 (in H2OH_2O) to 00 (in H2H_2). Since its oxidation number decreased, Hydrogen is reduced.
  3. Identify the Oxidizing Agent: Because H2OH_2O provides the oxygen that oxidizes the carbon and contains the hydrogen that gets reduced, H2OH_2O is the substance that causes oxidation. Therefore, H2OH_2O is the oxidizing agent.
Conclusion

The substance that is reduced is the oxidizing agent. Since H2OH_2O is reduced to H2H_2, it is the oxidizing agent.

Exam Tip

A simple way to remember this is the acronym OIL RIG:

  • Oxidation Is Loss (of electrons/increase in oxidation state).
  • Reduction Is Gain (of electrons/decrease in oxidation state). The substance that gets reduced is the oxidizing agent, and the substance that gets oxidized is the reducing agent.

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