JAMB 2011 Chemistry · Question 31

What is the concentration of a solution containing 2g of NaOH in 100cm3 of solution? [Na = 23, O = 16, H = 1]

Options

  1. A.0.40 mol dm−3dm^{-3}
  2. B.0.50 mol dm−3dm^{-3}
  3. C.0.05 mol dm−3dm^{-3}
  4. D.0.30 mol dm−3dm^{-3}

Answer: B. 0.50 mol dm−3dm^{-3}

Explanation written with AI and checked against the answer key

Analysis

To find the concentration of the solution, we need to determine how many moles of solute (NaOH) are present in a specific volume of solution (expressed in dm3dm^3).

Concept

The concentration (CC) in mol/dm3mol/dm^3 is calculated using the formula:

C=nVC = \frac{n}{V}

Where:

  • nn = number of moles of the solute
  • VV = volume of the solution in dm3dm^3

To find the number of moles (nn), we use:

n=massmolar massn = \frac{\text{mass}}{\text{molar mass}}
Step-by-Step Solution

Step 1: Calculate the molar mass of NaOH

  • Na = 23, O = 16, H = 1
  • Molar mass of NaOH = 23+16+1=40 g/mol23 + 16 + 1 = 40 \, g/mol

Step 2: Calculate the number of moles (nn) of NaOH

  • Mass given = 2 g2 \, g
  • n=2 g40 g/mol=0.05 moln = \frac{2 \, g}{40 \, g/mol} = 0.05 \, mol

Step 3: Convert the volume from cm3cm^3 to dm3dm^3

  • 1000 cm3=1 dm31000 \, cm^3 = 1 \, dm^3
  • 100 cm3=1001000 dm3=0.1 dm3100 \, cm^3 = \frac{100}{1000} \, dm^3 = 0.1 \, dm^3

Step 4: Calculate the concentration (CC)

  • C=0.05 mol0.1 dm3C = \frac{0.05 \, mol}{0.1 \, dm^3}
  • C=0.5 mol/dm3C = 0.5 \, mol/dm^3
Conclusion

The calculated concentration is 0.50 mol dm−3dm^{-3}. This matches option B.

Exam Tip

Always remember the conversion factor: 1 dm3=1000 cm31 \, dm^3 = 1000 \, cm^3. A common mistake in JAMB Chemistry is forgetting to convert cm3cm^3 to dm3dm^3, which leads to an answer that is 1000 times larger than the correct one. Also, ensure you always calculate the molar mass correctly from the atomic masses provided in the bracket!

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