JAMB 2011 Chemistry · Question 33

The arrangement of particles in crystal lattices can be studied using

Options

  1. A.X - rays
  2. B.γ - rays
  3. C.α - rays
  4. D.β - rays

Answer: A. X - rays

Explanation written with AI and checked against the answer key

Analysis

The question asks for the specific scientific tool or type of radiation used to determine the internal structure and arrangement of atoms or ions within a crystal lattice.

Concept Explanation

In chemistry and physics, a crystal lattice is a highly ordered, repeating three-dimensional arrangement of particles (atoms, ions, or molecules). Because these particles are packed extremely closely together (at the atomic scale), we need a probe with a wavelength similar to the distance between these particles to "see" them.

  • X-rays have wavelengths in the range of 0.01 to 10 nanometers, which corresponds perfectly to the spacing between atoms in a crystal. When X-rays strike a crystal, they undergo diffraction. By analyzing the diffraction pattern produced, scientists can calculate the precise positions of the atoms in the lattice. This technique is known as X-ray Crystallography.
  • Gamma (γ) rays have much shorter wavelengths and higher energy, making them difficult to control for this specific purpose.
  • Alpha (α) and Beta (β) particles are forms of ionizing radiation consisting of matter (helium nuclei and electrons, respectively) and are not suitable for diffraction studies of crystal structures.
Step-by-Step Solution
  1. Identify the goal: We need to measure the distance between atoms in a solid.
  2. Evaluate the options: • X-rays: Possess the correct wavelength to interact with atomic planes in a crystal lattice. • γ-rays: Too high-energy; they pass through or damage the sample rather than diffracting off the atomic planes. • α-rays and β-rays: These are particles with mass and charge; they are absorbed by the surface of the crystal and cannot penetrate to reveal the internal lattice structure.
  3. Conclusion: X-ray diffraction is the standard laboratory method used to study crystal structures.
Correct Answer

The correct option is A.

Exam Tip

Whenever you see a question about "crystal structure," "atomic spacing," or "diffraction patterns," immediately look for X-rays. Think of X-rays as the "microscope" for atoms!

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