WAEC 2023 Chemistry · Question 1

Consider the following reaction equation: 2SO3(g)→2SO2(g)+O22SO_3(g) → 2SO_2(g) + O_2(g) ∆H = +198 kJ/mol Which of the following statements about the reaction is correct?

Options

  1. A.198 kJ of energy is given off
  2. B.The reaction is exothermic
  3. C.The reaction container would feel warm.
  4. D.198 kJ of energy is absorbed

Answer: D. 198 kJ of energy is absorbed

Explanation written with AI and checked against the answer key

Step 1: Analyze the question We are given a thermochemical equation with ΔH = +198 kJ/mol and asked which statement about it is correct.

Step 2: The concept The sign of ΔH tells you whether a reaction is endothermic or exothermic:

  • ΔH positive (+): heat is absorbed from the surroundings → endothermic. The container feels cold.
  • ΔH negative (−): heat is released to the surroundings → exothermic. The container feels warm.

Step 3: Apply it to the reaction 2SO₃(g) → 2SO₂(g) + O₂(g) ΔH = +198 kJ/mol

Since ΔH is positive:

  • The reaction is endothermic.
  • Energy is absorbed (198 kJ for the equation as written, i.e., for 2 moles of SO₃ decomposing).
  • The surroundings lose heat, so the container would feel cool, not warm.

Step 4: Check each option

  • A. 198 kJ of energy is given off: Wrong. Energy is absorbed, not released.
  • B. The reaction is exothermic: Wrong. It is endothermic.
  • C. The reaction container would feel warm: Wrong. It would feel cold.
  • D. 198 kJ of energy is absorbed: Correct.

Answer: D

Exam tip: Remember "Positive = Put in" (heat is taken in, endothermic) and "Negative = Net out" (heat is given out, exothermic). Also, endothermic reactions feel cold because they draw heat from their surroundings.

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