WAEC 2022 Chemistry · Question 49
Which of the following statements about the standard hydrogen electrode is not correct?
Options
- A.The hydrogen gas is at a pressure of 1 atmosphere
- B.A solution containing 1 mol of H+ (aq) ions is used
- C.A platinum electrode is used
- D.The temperature is kept at 20 °C
Answer: D. The temperature is kept at 20 °C
Explanation written with AI and checked against the answer key
Analyze the question: We need the statement about the standard hydrogen electrode (SHE) that is not correct.
Concept: The SHE is the reference electrode used to measure standard electrode potentials. By definition its potential is exactly 0.00 V. The standard conditions are:
- Hydrogen gas at a pressure of 1 atm (101.3 kPa)
- H⁺(aq) solution at a concentration of 1 mol dm⁻³
- An inert platinum electrode, coated with platinum black, which adsorbs the hydrogen gas and conducts electrons
- A temperature of 25 °C (298 K)
Check each option:
- A. Hydrogen at 1 atm is correct.
- B. 1 mol dm⁻³ H⁺(aq) is correct.
- C. A platinum electrode is correct. It is inert and provides a surface for the reaction 2H⁺ + 2e⁻ ⇌ H₂.
- D. A temperature of 20 °C is not correct. The standard temperature is 25 °C (298 K).
Tip: Remember the SHE as "1, 1, Pt, 25": 1 atm, 1 mol dm⁻³, platinum, 25 °C. If an option gives a different temperature, such as 20 °C, it is probably the false statement.
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