WAEC 2022 Chemistry · Question 49

Which of the following statements about the standard hydrogen electrode is not correct?

Options

  1. A.The hydrogen gas is at a pressure of 1 atmosphere
  2. B.A solution containing 1 mol dm−3dm^{-3} of H+ (aq) ions is used
  3. C.A platinum electrode is used
  4. D.The temperature is kept at 20 °C

Answer: D. The temperature is kept at 20 °C

Explanation written with AI and checked against the answer key

Analyze the question: We need the statement about the standard hydrogen electrode (SHE) that is not correct.

Concept: The SHE is the reference electrode used to measure standard electrode potentials. By definition its potential is exactly 0.00 V. The standard conditions are:

  • Hydrogen gas at a pressure of 1 atm (101.3 kPa)
  • H⁺(aq) solution at a concentration of 1 mol dm⁻³
  • An inert platinum electrode, coated with platinum black, which adsorbs the hydrogen gas and conducts electrons
  • A temperature of 25 °C (298 K)

Check each option:

  • A. Hydrogen at 1 atm is correct.
  • B. 1 mol dm⁻³ H⁺(aq) is correct.
  • C. A platinum electrode is correct. It is inert and provides a surface for the reaction 2H⁺ + 2e⁻ ⇌ H₂.
  • D. A temperature of 20 °C is not correct. The standard temperature is 25 °C (298 K).

Tip: Remember the SHE as "1, 1, Pt, 25": 1 atm, 1 mol dm⁻³, platinum, 25 °C. If an option gives a different temperature, such as 20 °C, it is probably the false statement.

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