WAEC 2021 Chemistry · Question 32
A molecular of phosphorus is
Options
- A.diatomic
- B.triatomic
- C.tetraatomic
- D.monoatomic
Answer: C. tetraatomic
Explanation written with AI and checked against the answer key
Analyze the question: The question asks about the atomicity of a phosphorus molecule, meaning how many atoms are joined together in one molecule of phosphorus.
Explain the concept: Atomicity is the number of atoms in one molecule of an element. Common examples:
- Monoatomic: noble gases (He, Ne, Ar)
- Diatomic: H₂, O₂, N₂, Cl₂
- Triatomic: O₃ (ozone)
- Tetraatomic: P₄ (white phosphorus)
- Octaatomic: S₈ (sulphur)
Solution:
- Phosphorus (in its common form, white phosphorus) does not exist as single atoms or pairs.
- Four phosphorus atoms bond together in a tetrahedral arrangement, with each atom bonded to the other three.
- The molecular formula is therefore P₄.
- Since there are 4 atoms per molecule, phosphorus is tetraatomic.
Nitrogen, which is in the same group, is diatomic (N₂) because it forms strong triple bonds. Phosphorus atoms are larger and form weaker π bonds, so they prefer the P₄ tetrahedral structure.
Answer: The correct option is C. tetraatomic.
Tip: Remember the atomicity sequence with the examples: "He (1), O₂ (2), O₃ (3), P₄ (4), S₈ (8)." WASSCE often asks about P₄ and S₈, so memorize these two.
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