WAEC 2021 Chemistry · Question 32

A molecular of phosphorus is

Options

  1. A.diatomic
  2. B.triatomic
  3. C.tetraatomic
  4. D.monoatomic

Answer: C. tetraatomic

Explanation written with AI and checked against the answer key

Analyze the question: The question asks about the atomicity of a phosphorus molecule, meaning how many atoms are joined together in one molecule of phosphorus.

Explain the concept: Atomicity is the number of atoms in one molecule of an element. Common examples:

  • Monoatomic: noble gases (He, Ne, Ar)
  • Diatomic: H₂, O₂, N₂, Cl₂
  • Triatomic: O₃ (ozone)
  • Tetraatomic: P₄ (white phosphorus)
  • Octaatomic: S₈ (sulphur)

Solution:

  1. Phosphorus (in its common form, white phosphorus) does not exist as single atoms or pairs.
  2. Four phosphorus atoms bond together in a tetrahedral arrangement, with each atom bonded to the other three.
  3. The molecular formula is therefore P₄.
  4. Since there are 4 atoms per molecule, phosphorus is tetraatomic.

Nitrogen, which is in the same group, is diatomic (N₂) because it forms strong triple bonds. Phosphorus atoms are larger and form weaker π bonds, so they prefer the P₄ tetrahedral structure.

Answer: The correct option is C. tetraatomic.

Tip: Remember the atomicity sequence with the examples: "He (1), O₂ (2), O₃ (3), P₄ (4), S₈ (8)." WASSCE often asks about P₄ and S₈, so memorize these two.

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