WAEC 2020 Chemistry · Question 46

Which of the following standard conditions is not correct about energy changes?

Options

  1. A.Standard temperature is 298K
  2. B.B. Standard pressure is 1 atm
  3. C.Concentration of solution must be 1 mol/dm3^3
  4. D.ΔH at 298 K is the activation energy

Answer: D. ΔH at 298 K is the activation energy

Explanation written with AI and checked against the answer key

Analyzing the question: We need the statement that is NOT correct about the standard conditions used for energy changes (thermochemistry).

Concept: Standard conditions for measuring enthalpy changes (ΔH°) are:

  • Temperature: 298 K (25 °C)
  • Pressure: 1 atm (101.325 kPa, about 100 kPa)
  • Concentration of solutions: 1 mol/dm³
  • Substances in their standard physical states

Checking each option:

  • A. Standard temperature is 298 K. Correct. This is the standard temperature for thermochemical measurements.
  • B. Standard pressure is 1 atm. Correct. This is the standard pressure used in WASSCE chemistry.
  • C. Concentration of solution must be 1 mol/dm³. Correct. Solutions must have unit concentration.
  • D. ΔH at 298 K is the activation energy. Incorrect. ΔH is the enthalpy change, the difference between the energy of the products and the energy of the reactants (ΔH = H_products − H_reactants). Activation energy (Ea) is the minimum energy the reactants need for the reaction to occur, which is the energy barrier from the reactants up to the transition state. They are different quantities, and ΔH does not become the activation energy just because it is measured at 298 K.

Answer: D

Tip: Remember the standard conditions as "298, 1, 1": 298 K, 1 atm, 1 mol/dm³. Also keep in mind that ΔH is the overall energy difference, while activation energy is the energy hill the reactants must climb. Any option that mixes the two up is likely to be the wrong statement.

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