WAEC 2020 Chemistry · Question 22

Consider the reaction represented by the following equation: AgNO 3 + NaCl → AgCl + NaNO 3 . The steps that…

Question

Consider the reaction represented by the following equation: AgNO3_3 + NaCl → AgCl + NaNO3_3. The steps that could be taken to obtain pure dry sample of AgCI (s) from the mixture includes

  1. A.heating to saturation and drying
  2. B.filtering and evaporation to dryness
  3. C.filtering, washing and drying
  4. D.crystallizing and allowing to cool

Answer: C. filtering, washing and drying

Explanation written with AI and checked against the answer key

Analyze the question: When aqueous AgNO₃ reacts with aqueous NaCl, AgCl forms as an insoluble white precipitate, while NaNO₃ stays dissolved in the water. We need the steps to get pure, dry AgCl solid.

Concept: This is a precipitation reaction, so the separation method depends on solubility:

  • AgCl is insoluble in water, so it is a solid precipitate.
  • NaNO₃ is soluble, so it remains in solution (the filtrate).

Solution:

  1. Filter the mixture. The AgCl stays on the filter paper as the residue, and the NaNO₃ solution passes through as the filtrate.
  2. Wash the residue with distilled water. This removes any NaNO₃ solution still clinging to the AgCl, which makes it pure.
  3. Dry the residue, in an oven or between filter papers, to get dry AgCl.

Checking the other options:

  • A. Heating to saturation is used for obtaining crystals of a dissolved solute, not for separating a precipitate.
  • B. Evaporating to dryness would leave NaNO₃ mixed in with the AgCl, so the sample would be impure.
  • D. Crystallizing and cooling applies to soluble salts, not to an insoluble precipitate.

Answer: Option C, filtering, washing and drying.

Tip: For an insoluble solid mixed with a soluble one, remember F-W-D: Filter, Wash, Dry. Use evaporation or crystallization only to recover the soluble substance from the filtrate.

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