WAEC 2020 Chemistry · Question 22
Consider the reaction represented by the following equation: AgNO 3 + NaCl → AgCl + NaNO 3 . The steps that…
Question
Consider the reaction represented by the following equation: AgNO + NaCl → AgCl + NaNO. The steps that could be taken to obtain pure dry sample of AgCI (s) from the mixture includes
- A.heating to saturation and drying
- B.filtering and evaporation to dryness
- C.filtering, washing and drying
- D.crystallizing and allowing to cool
Answer: C. filtering, washing and drying
Explanation written with AI and checked against the answer key
Analyze the question: When aqueous AgNO₃ reacts with aqueous NaCl, AgCl forms as an insoluble white precipitate, while NaNO₃ stays dissolved in the water. We need the steps to get pure, dry AgCl solid.
Concept: This is a precipitation reaction, so the separation method depends on solubility:
- AgCl is insoluble in water, so it is a solid precipitate.
- NaNO₃ is soluble, so it remains in solution (the filtrate).
Solution:
- Filter the mixture. The AgCl stays on the filter paper as the residue, and the NaNO₃ solution passes through as the filtrate.
- Wash the residue with distilled water. This removes any NaNO₃ solution still clinging to the AgCl, which makes it pure.
- Dry the residue, in an oven or between filter papers, to get dry AgCl.
Checking the other options:
- A. Heating to saturation is used for obtaining crystals of a dissolved solute, not for separating a precipitate.
- B. Evaporating to dryness would leave NaNO₃ mixed in with the AgCl, so the sample would be impure.
- D. Crystallizing and cooling applies to soluble salts, not to an insoluble precipitate.
Answer: Option C, filtering, washing and drying.
Tip: For an insoluble solid mixed with a soluble one, remember F-W-D: Filter, Wash, Dry. Use evaporation or crystallization only to recover the soluble substance from the filtrate.
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