WAEC 2018 Chemistry · Question 45
When zinc is added to AgNO solution, crystals of silver forms on the zinc surface. This indicates that zinc is
Options
- A.oxidised
- B.reduced
- C.decomposed
- D.dissociated
Answer: A. oxidised
Explanation written with AI and checked against the answer key
Analyze the question: Zinc is placed in silver nitrate solution, and silver crystals form on the zinc. We need to say what happens to the zinc.
Concept: This is a displacement (redox) reaction. A more reactive metal displaces a less reactive metal from its salt solution.
- Oxidation = loss of electrons (oxidation number increases)
- Reduction = gain of electrons (oxidation number decreases)
In the reactivity series, zinc is above silver, so zinc is more reactive and displaces silver.
Solution:
Overall equation: Zn(s) + 2AgNO₃(aq) → Zn(NO₃)₂(aq) + 2Ag(s)
Half-equations:
- Zn → Zn²⁺ + 2e⁻ (zinc loses electrons, so it is oxidised)
- Ag⁺ + e⁻ → Ag (silver ions gain electrons, so they are reduced, forming the silver crystals)
Zinc's oxidation number goes from 0 to +2, which confirms oxidation. Zinc is also the reducing agent, because it supplies the electrons that reduce Ag⁺.
Checking the options:
- A. Oxidised: correct, since zinc loses electrons.
- B. Reduced: this is what happens to silver ions, not zinc.
- C. Decomposed: zinc is an element and does not break down into simpler substances.
- D. Dissociated: this applies to ionic compounds splitting into ions in solution, not to a metal reacting.
Answer: A. oxidised
Tip: Use OIL RIG: Oxidation Is Loss, Reduction Is Gain (of electrons). When a metal dissolves into solution as ions, it has been oxidised. The metal that appears as a deposit, here silver, has been reduced from its ions.
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