WAEC 2018 Chemistry · Question 36
The number of Hydrogen ions in 1.0 of 0.02 tetraoxosulphate(VI) acid is
Options
- A.
- B.
- C.
- D.
Answer: C.
Explanation written with AI and checked against the answer key
Analyze the question: We need the number of H⁺ ions in 1.0 dm³ of 0.02 mol/dm³ H₂SO₄ (tetraoxosulphate(VI) acid).
Concept: H₂SO₄ is a strong dibasic acid. Each mole of H₂SO₄ gives 2 moles of H⁺ when it dissociates completely:
H₂SO₄ → 2H⁺ + SO₄²⁻
Number of particles = moles × Avogadro's number (N_A).
Solution:
- Moles of H₂SO₄ = concentration × volume = 0.02 × 1.0 = 0.02 mol
- Moles of H⁺ = 2 × 0.02 = 0.04 mol
- Number of H⁺ ions = 0.04 × 6.02 × 10²³ = 0.2408 × 10²⁴ ≈ 2.4 × 10²²
Check: 0.04 × 6.02 × 10²³ = 0.2408 × 10²³ = 2.408 × 10²². This gives 2.4 × 10²².
(Be careful with the powers of ten: 0.04 = 4 × 10⁻², so 4 × 6.02 × 10²³ × 10⁻² = 24.08 × 10²¹ = 2.4 × 10²².)
Answer: The number of hydrogen ions is 2.4 × 10²², which is option C.
Tip: For acids, always check the basicity (number of replaceable H⁺). H₂SO₄ gives 2 H⁺, so multiply the moles of acid by 2. Also, convert decimals to standard form before multiplying so you don't slip on powers of ten. Option A (1.2 × 10²²) is the trap from forgetting the factor of 2.
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