WAEC 2018 Chemistry · Question 42
Ethene is produced from ethanol by
Options
- A.decomposition
- B.hydrolysis
- C.ozonolysis
- D.dehydration
Answer: D. dehydration
Explanation written with AI and checked against the answer key
Analyze the question: It asks which process converts ethanol (C₂H₅OH) into ethene (C₂H₄).
Concept: When ethanol is heated with excess concentrated sulphuric acid at about 170 °C (or passed over hot alumina, Al₂O₃), a water molecule is removed from each ethanol molecule. Removing water from a compound is called dehydration. It is an elimination reaction that forms a double bond.
Solution:
C₂H₅OH → C₂H₄ + H₂O (conc. H₂SO₄, 170 °C)
- The –OH group is removed from one carbon.
- An –H is removed from the neighbouring carbon.
- Together they leave as H₂O, and a C=C double bond forms.
Checking the options:
- A. Decomposition: This is too general. It means breaking a compound into simpler substances, and it does not name the specific process of removing water.
- B. Hydrolysis: This is the reaction of a compound with water to break it down. It is the opposite of what happens here, because water is removed, not added.
- C. Ozonolysis: This is the cleavage of C=C bonds by ozone. It does not apply here.
- D. Dehydration: Correct, because water is removed from ethanol.
**Answer: D. Dehydration.
Exam tip: Remember "Ethanol → Ethene = Dehydration (lose water)." The reverse reaction, ethene + steam → ethanol, is hydration. In WASSCE, a conc. H₂SO₄ catalyst with heat usually signals a dehydration question.
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