WAEC 2017 Chemistry · Question 37

The real harmful effect of the release of chlorofluorocarbons into the atmosphere is that it eventually causes

Options

  1. A.excessive ultraviolet light from the sun to reach the earth surface
  2. B.excessive release of infrared light from the sun to the earth surface
  3. C.corrosive effect of the chemicals on humans and animals
  4. D.acidic effect of chemicals on humans

Answer: A. excessive ultraviolet light from the sun to reach the earth surface

Explanation written with AI and checked against the answer key

Step 1: Analyze the question The question asks about the real harmful effect of chlorofluorocarbons (CFCs) when released into the atmosphere.

Step 2: The concept CFCs (found in old refrigerators, air conditioners, aerosol sprays and foam) are very stable, so they drift up into the stratosphere. There, strong ultraviolet (UV) radiation breaks the C-Cl bonds and releases chlorine free radicals:

CFCl₃ → CFCl₂• + Cl•

The chlorine radicals then destroy ozone (O₃):

Cl• + O₃ → ClO• + O₂ ClO• + O → Cl• + O₂

The chlorine radical is regenerated, so one Cl• can destroy thousands of ozone molecules. This causes depletion of the ozone layer.

Step 3: Why this matters The ozone layer acts as a shield that absorbs most of the harmful UV-B and UV-C radiation from the sun. When it thins, more UV reaches the earth's surface. This leads to:

  • skin cancer and cataracts in humans
  • damage to crops and plankton
  • other harmful effects on living things

Step 4: Check the options

  • A. Excessive UV light reaching the earth's surface. Correct, this is the direct result of ozone depletion.
  • B. Infrared light is related to heat and global warming (greenhouse effect), not the main ozone-related effect. CFCs are greenhouse gases, but "the real harmful effect" points to ozone depletion.
  • C. CFCs are not corrosive to living things. They are fairly inert.
  • D. CFCs do not cause an acidic effect. That is associated with SO₂ and NOₓ (acid rain).

Answer: A

Exam tip: Remember CFC → Cl radicals → ozone depletion → more UV. Associate "ozone" with "UV" and "CO₂/methane" with "infrared/global warming". WAEC and JAMB often test this contrast.

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