WAEC 2017 Chemistry · Question 32
The IUPAC name for the compound is
Options
- A.1- chloropropanol
- B.2-chloropropanol
- C.1-chloroethanol
- D.2-chloroethanol
Answer: D. 2-chloroethanol
Explanation written with AI and checked against the answer key
Step 1: Analyze the question We need the IUPAC name of ClCH₂CH₂OH. Count the carbons, find the principal functional group, then number the chain.
Step 2: Concept IUPAC naming rules:
- The parent chain is the longest carbon chain. Here there are 2 carbons, so the parent is ethane.
- The principal functional group (the –OH, which gives an alcohol, suffix -ol) gets the lowest possible number.
- Substituents such as chlorine (prefix chloro-) are numbered according to that chain numbering.
Step 3: Solution Structure: Cl–CH₂–CH₂–OH
- Two carbons means ethane, so the parent is ethanol.
- Number from the end nearest the –OH group, so the carbon bearing –OH is C-1. • C-1: CH₂OH • C-2: CH₂Cl
- The chlorine is on C-2, so the name is 2-chloroethanol.
Why not the others?
- A and B say "propanol", which would need 3 carbons, but we have only 2.
- C says 1-chloroethanol, which would be Cl and OH on the same carbon (CH₃CH(Cl)OH). That is a different compound.
Answer: D. 2-chloroethanol
Tip: In naming alcohols, the –OH always gets the lowest number. Then place the other substituents using that numbering. Always count carbons first, because that removes wrong options like "propanol" immediately.
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