WAEC 2017 Chemistry · Question 32

The IUPAC name for the compound ClCH2CH2OHClCH_{2}CH_{2}OH is

Options

  1. A.1- chloropropanol
  2. B.2-chloropropanol
  3. C.1-chloroethanol
  4. D.2-chloroethanol

Answer: D. 2-chloroethanol

Explanation written with AI and checked against the answer key

Step 1: Analyze the question We need the IUPAC name of ClCH₂CH₂OH. Count the carbons, find the principal functional group, then number the chain.

Step 2: Concept IUPAC naming rules:

  • The parent chain is the longest carbon chain. Here there are 2 carbons, so the parent is ethane.
  • The principal functional group (the –OH, which gives an alcohol, suffix -ol) gets the lowest possible number.
  • Substituents such as chlorine (prefix chloro-) are numbered according to that chain numbering.

Step 3: Solution Structure: Cl–CH₂–CH₂–OH

  1. Two carbons means ethane, so the parent is ethanol.
  2. Number from the end nearest the –OH group, so the carbon bearing –OH is C-1. • C-1: CH₂OH • C-2: CH₂Cl
  3. The chlorine is on C-2, so the name is 2-chloroethanol.

Why not the others?

  • A and B say "propanol", which would need 3 carbons, but we have only 2.
  • C says 1-chloroethanol, which would be Cl and OH on the same carbon (CH₃CH(Cl)OH). That is a different compound.

Answer: D. 2-chloroethanol

Tip: In naming alcohols, the –OH always gets the lowest number. Then place the other substituents using that numbering. Always count carbons first, because that removes wrong options like "propanol" immediately.

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