WAEC 2017 Chemistry · Question 7

Pauli exclusion principle is related to

Options

  1. A.quantity of electrons in the valence shell
  2. B.filling the orbitals with lower energy first
  3. C.the filling of degenerated orbitals
  4. D.quantum numbers of electrons

Answer: D. quantum numbers of electrons

Explanation written with AI and checked against the answer key

Step 1: Analyze the question The question asks what the Pauli exclusion principle is related to. Think about what the principle actually states.

Step 2: Explain the concept The Pauli exclusion principle states that no two electrons in the same atom can have the same set of all four quantum numbers (n, l, mₗ, mₛ).

A key consequence is that an orbital can hold a maximum of two electrons, and these must have opposite spins (+½ and -½).

Step 3: Check each option

  • A. Quantity of electrons in the valence shell: This relates to the octet rule and valency, not Pauli's principle.
  • B. Filling the orbitals with lower energy first: This is the Aufbau principle.
  • C. The filling of degenerate orbitals: This is Hund's rule of maximum multiplicity. Electrons occupy degenerate orbitals singly before pairing up.
  • D. Quantum numbers of electrons: This matches Pauli's principle, since it restricts how the four quantum numbers can be combined for electrons in an atom.

Step 4: Answer

Tip: Link each principle to its key idea:

  • Pauli → Pairs/quantum numbers (no two electrons have the same four)
  • Aufbau → build up from lowest energy
  • Hund → Half-fill degenerate orbitals first (singly, like passengers taking empty seats on a bus before sharing)

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