WAEC 2016 Chemistry · Question 18
Which of the following factors will affect the rate of the reaction represented by the following equation?…
Question
Which of the following factors will affect the rate of the reaction represented by the following equation? 2HCl(aq) + CaCO3(s) CaCl2(aq) + H2O(1) + CO2(g) I. Pressure II.Concentration III. Nature of reactants IV. Temperature
- A.I and II only
- B.II, III and IV only
- C.I, II and III only
- D.I, II. III and IV
Answer: B. II, III and IV only
Explanation written with AI and checked against the answer key
Analyze the question: We need the factors that affect the rate of the reaction between dilute hydrochloric acid (aqueous) and calcium carbonate (solid), which produces CO₂ gas.
Concept: Reaction rate depends on how often and how effectively particles collide. The main factors are:
- Concentration of reactants in solution (higher concentration means more frequent collisions)
- Temperature (higher temperature means more energetic particles and more effective collisions)
- Nature of reactants (different substances react at different intrinsic rates)
- Surface area of solids (not listed here)
- Catalyst (not listed here)
- Pressure, which matters only when the reactants are gases
Step-by-step evaluation:
I. Pressure: The reactants are an aqueous solution and a solid. The only gas, CO₂, is a product. Pressure changes affect the rate significantly only when gaseous reactants are involved, so pressure is not a significant factor here.
II. Concentration: Changing the concentration of HCl changes the rate. This is a factor.
III. Nature of reactants: The identity of the reactants (an acid and a metal carbonate) determines how fast the reaction proceeds. This is a factor.
IV. Temperature: Heating speeds up the reaction. This is a factor.
So the factors are II, III and IV only.
Answer: B
Tip: In rate-of-reaction questions, check the physical states first. Pressure matters only if gaseous reactants are present. A gas appearing only as a product (like CO₂ here) does not make pressure a factor. WAEC often uses this trap.
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