WAEC 2015 Chemistry · Question 27
The number of unpaired electrons in an atom of an element 8Q is _______?
Options
- A.2
- B.4
- C.6
- D.8
Answer: A. 2
Explanation written with AI and checked against the answer key
Analyze the question: Element ₈Q has atomic number 8, so it is oxygen with 8 electrons. We need the number of unpaired electrons in its ground state.
Concept: Electrons fill orbitals in order of increasing energy (Aufbau principle). Within a subshell, electrons occupy separate orbitals singly first, with parallel spins, before pairing up (Hund's rule).
Solution:
- Electron configuration of oxygen: 1s² 2s² 2p⁴
- 1s² is a full orbital, so both electrons are paired.
- 2s² is a full orbital, so both electrons are paired.
- 2p⁴: the 2p subshell has three orbitals (2pₓ, 2p_y, 2p_z). By Hund's rule, the first three electrons go in singly, and the fourth pairs up with one of them:
- 2pₓ: ↑↓ (paired)
- 2p_y: ↑ (unpaired)
- 2p_z: ↑ (unpaired)
- Number of unpaired electrons = 2
This also matches oxygen's valency of 2. It forms two bonds, as in H₂O.
Answer: The correct option is A. 2.
Tip: For p-block elements, count the p electrons. For p¹ to p³ the unpaired electrons equal the p electron count. For p⁴ to p⁶ the unpaired electrons are 6 minus the p count. Here p⁴ gives 6 − 4 = 2.
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