WAEC 2014 Chemistry · Question 14
Which of the following relationships correctly expresses the Boyle's law?
Options
- A.P V at constant T
- B.V T at constant P
- C.P at constant T
- D.V at constant P
Answer: C. P at constant T
Explanation written with AI and checked against the answer key
Step 1: Analyze the question You are asked which expression correctly states Boyle's law.
Step 2: The concept Boyle's law says that for a fixed mass of gas at constant temperature, the volume is inversely proportional to the pressure.
Mathematically:
P ∝ 1/V (at constant T)
or equivalently, PV = constant, so P₁V₁ = P₂V₂.
This means that if you squeeze a gas into half the volume, its pressure doubles.
Step 3: Check each option
- A. P ∝ V at constant T: Wrong. This is direct proportionality, but Boyle's law is an inverse relationship.
- B. V ∝ T at constant P: This is Charles's law, not Boyle's.
- C. P ∝ 1/V at constant T: Correct. Pressure is inversely proportional to volume at constant temperature.
- D. V ∝ 1/T at constant P: Wrong. Volume is directly proportional to T (Charles's law), not inversely.
Step 4: Answer
Tip: Remember the pairs of laws by what is held constant:
- Boyle: constant T, so P and V are inverse (think "B" for "Bounce back": squeeze it and pressure goes up).
- Charles: constant P, so V ∝ T.
- Pressure law (Gay-Lussac): constant V, so P ∝ T.
If the question mentions "constant temperature," the answer almost always involves an inverse relationship between P and V.
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