WAEC 2014 Chemistry · Question 38

The shape of CH4 is

Options

  1. A.linear
  2. B.planar
  3. C.pyramidal
  4. D.tetrahedral

Answer: D. tetrahedral

Explanation written with AI and checked against the answer key

Step 1: Analyze the question You're asked for the molecular shape of methane, CH₄.

Step 2: The concept (VSEPR theory) Electron pairs around a central atom repel each other and arrange themselves as far apart as possible. The shape depends on the number of bonding pairs and lone pairs on the central atom.

Step 3: Solution

  • Carbon (atomic number 6) has the configuration 1s² 2s² 2p², so it has 4 valence electrons.
  • Each of the 4 electrons pairs with an electron from a hydrogen atom, forming 4 C-H covalent bonds.
  • There are 4 bonding pairs and 0 lone pairs around carbon.
  • Four electron pairs are farthest apart when they point to the corners of a tetrahedron.
  • The H-C-H bond angle is 109.5°.

Comparison with other shapes:

  • Linear (e.g., BeCl₂, CO₂): 2 electron pairs, 180°
  • Planar/trigonal planar (e.g., BF₃): 3 pairs, 120°
  • Pyramidal (e.g., NH₃): 3 bonding pairs + 1 lone pair, about 107°
  • Tetrahedral (e.g., CH₄): 4 bonding pairs, 109.5°

Step 4: Answer The shape of CH₄ is tetrahedral, which is option D.

Tip: Count the electron pairs on the central atom.

  • 4 bonding pairs and no lone pairs gives tetrahedral (CH₄).
  • 3 bonding pairs and 1 lone pair gives pyramidal (NH₃).
  • 2 bonding pairs and 2 lone pairs gives bent/V-shaped (H₂O).

Remember: lone pairs change the shape, so with no lone pairs the shape follows directly from the number of bonds.

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