WAEC 2014 Chemistry · Question 31
The IUPAC name of the following organic compound is HOOC - COOH
Options
- A.ethan - 1, 2 -dioc acid
- B.ethanoic acid
- C.oxalic acid
- D.propan - 1,2-dioic acid
Answer: A. ethan - 1, 2 -dioc acid
Explanation written with AI and checked against the answer key
Step 1: Analyze the question
The compound is HOOC-COOH. It has two carbon atoms, and each carbon is part of a carboxylic acid group (-COOH). We need its IUPAC name, not its common (trivial) name.
Step 2: Concept
- Parent chain: 2 carbons, so "eth-" (ethane).
- For a carboxylic acid, the ending "-e" of the alkane is replaced by "-oic acid".
- With two -COOH groups, we keep the "e" and use "-dioic acid": ethanedioic acid.
- The carboxyl carbons are always carbon 1 of the chain, so here they are C1 and C2.
Step 3: Check the options
- A. ethan-1,2-dioc acid: This is the closest to the correct name, ethane-1,2-dioic acid (ethanedioic acid). The spelling "dioc" is a typo for "dioic", but it is the only option with the right parent chain and two acid groups.
- B. ethanoic acid: This is CH₃COOH, with only one acid group. Wrong.
- C. oxalic acid: This is the correct common (trivial) name for HOOC-COOH, but not the IUPAC name. Wrong for this question.
- D. propan-1,2-dioic acid: This has 3 carbons. Wrong.
Step 4: Answer
The IUPAC name is ethane-1,2-dioic acid (ethanedioic acid), which matches option A.
Tip: Whenever a question says "IUPAC name", avoid common names like oxalic acid, formic acid, or acetic acid. Count the carbons, then add the correct suffix: "-oic acid" for one acid group and "-dioic acid" for two. Remember the pair: oxalic acid is the common name, ethanedioic acid is the IUPAC name.
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