WAEC 2014 Chemistry · Question 3

If 0.20 mol dm−3dm^{-3} NaOH(aq) was evaporated to yield 5.0g of solid NaOH, calculate the volume of NaOH (aq) used. (Na = 23.0,O = 16:0; H = 1.00)

Options

  1. A.600cm−3cm^{-3}
  2. B.625cm3
  3. C.10003
  4. D.1600 cm 3

Answer: B. 625cm3

Explanation written with AI and checked against the answer key

Analyze the question: A NaOH solution of concentration 0.20 mol/dm³ was evaporated and gave 5.0 g of solid NaOH. We need the volume of solution that contained this mass of NaOH.

Concept:

  • Moles = mass ÷ molar mass
  • Volume = moles ÷ concentration

Solution:

  1. Molar mass of NaOH = 23.0 + 16.0 + 1.00 = 40.0 g/mol
  1. Moles of NaOH = 5.0 ÷ 40.0 = 0.125 mol
  1. Volume = n ÷ C = 0.125 ÷ 0.20 = 0.625 dm³
  1. Convert to cm³: 0.625 × 1000 = 625 cm³

Answer: The volume is 625 cm³, which is option B.

Tip: For "find the volume" questions, follow the chain mass → moles → volume. Remember that 1 dm³ = 1000 cm³, so multiply by 1000 at the end. Always check that your units match the options before choosing.

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