WAEC 2011 Chemistry · Question 35
The bond formed when two electrons that are shared between two atoms are donated by only one of the atoms is
Options
- A.covalent
- B.dative
- C.ionic
- D.metalic
Answer: B. dative
Explanation written with AI and checked against the answer key
Analyze the question: It asks for the type of bond in which the shared pair of electrons comes from only one atom.
Concept:
- Ionic bond: electrons are transferred from one atom to another, forming oppositely charged ions.
- Covalent bond: each atom contributes one electron to the shared pair.
- Dative (coordinate) bond: both shared electrons come from one atom, the donor. The other atom, the acceptor, must have an empty orbital.
- Metallic bond: positive metal ions are held together by a "sea" of delocalised electrons.
Solution:
- The two electrons are shared, so the bond is not ionic and not metallic.
- Both electrons come from only one atom, so it is not an ordinary covalent bond, where each atom gives one electron.
- This is the definition of a dative (coordinate covalent) bond.
Examples:
- Ammonium ion, NH₄⁺: the lone pair on N in NH₃ is donated to H⁺ (which has an empty orbital).
- Hydroxonium ion, H₃O⁺: the lone pair on O in H₂O is donated to H⁺.
An ordinary covalent bond is technically also "shared electrons", but the specific detail that only one atom donates both electrons points to the dative bond.
Answer: B. dative
Exam tip: Remember "Dative = Donor". If one atom donates both electrons in the shared pair, it is dative. Look for lone-pair donors like NH₃ and H₂O, and an acceptor like H⁺.
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