WAEC 2010 Chemistry · Question 20
The IUPAC name of C2H6COOC2,/sub>H6 is
Options
- A.ethyethanoate
- B.ethylproanoate
- C.propylethanoate
- D.propylpropanoate
Answer: B. ethylproanoate
Explanation written with AI and checked against the answer key
The formula is garbled ("C2H6COOC2,/sub>H6"), so we first need to work out what was intended.
Step 1: Interpret the formula The most likely intended formula is C₂H₅COOC₂H₅. Subscripts of 6 are impossible for an ethyl group, which must be C₂H₅. (Note: the written "C2H6" is a typo for C₂H₅.)
Step 2: Recall how esters are named An ester has the general form R-COO-R'.
- The R' group (attached to the O) is named first, as an alkyl name.
- The R-COO part (the acid part) is named second, ending in "-oate".
Step 3: Identify each part
- Acid part: C₂H₅COO-. This has the carbon chain of the carboxyl carbon plus the C₂H₅ group, which is 3 carbons in total, so it comes from propanoic acid and is named propanoate.
- Alkyl part: -C₂H₅ is ethyl.
Step 4: Combine the names The name is ethyl propanoate.
Step 5: Check against the options
- A. "ethyethanoate" would be CH₃COOC₂H₅, which has 2 carbons in the acid part, so it does not match.
- B. "ethylproanoate" is a misspelling of ethyl propanoate, but it is clearly the intended option.
- C. Propyl ethanoate is CH₃COOC₃H₇, so it does not match.
- D. Propyl propanoate is C₂H₅COOC₃H₇, so it does not match.
Exam tip: Name an ester "backwards" from how it is written. Read the part after the O first (alkyl), then name the acid part and change "-oic acid" to "-oate". Count the carbons of the acid part including the C=O carbon.
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