NECO 2009 Chemistry · Question 26
When air is passed through alkaline pyrogallol and then lime water, the gases left are
Options
- A.nitrogen and carbon (IV) oxide
- B.nitrogen and noble gases
- C.nitrogen and oxygen
- D.nitrogen, carbon (VI) oxide and noble gases
- E.the noble gases
Answer: B. nitrogen and noble gases
Explanation written with AI and checked against the answer key
Analyze the question: Air is passed through two reagents in sequence. We need to find which gases are left after both have absorbed what they react with.
Concept:
- Air contains roughly 78% nitrogen, 21% oxygen, 0.03% carbon (IV) oxide, about 1% noble gases (mainly argon), plus water vapour.
- Alkaline pyrogallol absorbs oxygen. It also absorbs CO₂, because it is alkaline.
- Lime water (calcium hydroxide solution) absorbs carbon (IV) oxide, turning milky as CaCO₃ forms: Ca(OH)₂ + CO₂ → CaCO₃ + H₂O
Step-by-step:
- Start with air: N₂, O₂, CO₂, noble gases.
- Pass through alkaline pyrogallol: O₂ is removed, and the alkaline medium also takes up CO₂. Left: N₂, noble gases (and CO₂ if any survives).
- Pass through lime water: any remaining CO₂ is removed. Left: N₂ and noble gases.
Nitrogen is unreactive towards both reagents, and the noble gases are inert, so they pass through unchanged.
Checking the options:
- A: CO₂ is absorbed, so it is not left. Wrong.
- B: Nitrogen and noble gases is exactly what remains. Correct.
- C: Oxygen is absorbed by pyrogallol. Wrong.
- D: CO₂ is absorbed (and "carbon (VI) oxide" does not exist anyway). Wrong.
- E: Nitrogen is not absorbed, so it remains too. Wrong.
**Answer: B.
Exam tip: Remember the absorbers: alkaline pyrogallol → oxygen, lime water or KOH → CO₂, anhydrous CaCl₂ or conc. H₂SO₄ → water vapour. After removing O₂, CO₂ and water, what is left is nitrogen plus the noble gases.
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