NECO 2009 Chemistry · Question 26

When air is passed through alkaline pyrogallol and then lime water, the gases left are

Options

  1. A.nitrogen and carbon (IV) oxide
  2. B.nitrogen and noble gases
  3. C.nitrogen and oxygen
  4. D.nitrogen, carbon (VI) oxide and noble gases
  5. E.the noble gases

Answer: B. nitrogen and noble gases

Explanation written with AI and checked against the answer key

Analyze the question: Air is passed through two reagents in sequence. We need to find which gases are left after both have absorbed what they react with.

Concept:

  • Air contains roughly 78% nitrogen, 21% oxygen, 0.03% carbon (IV) oxide, about 1% noble gases (mainly argon), plus water vapour.
  • Alkaline pyrogallol absorbs oxygen. It also absorbs CO₂, because it is alkaline.
  • Lime water (calcium hydroxide solution) absorbs carbon (IV) oxide, turning milky as CaCO₃ forms: Ca(OH)₂ + CO₂ → CaCO₃ + H₂O

Step-by-step:

  1. Start with air: N₂, O₂, CO₂, noble gases.
  2. Pass through alkaline pyrogallol: O₂ is removed, and the alkaline medium also takes up CO₂. Left: N₂, noble gases (and CO₂ if any survives).
  3. Pass through lime water: any remaining CO₂ is removed. Left: N₂ and noble gases.

Nitrogen is unreactive towards both reagents, and the noble gases are inert, so they pass through unchanged.

Checking the options:

  • A: CO₂ is absorbed, so it is not left. Wrong.
  • B: Nitrogen and noble gases is exactly what remains. Correct.
  • C: Oxygen is absorbed by pyrogallol. Wrong.
  • D: CO₂ is absorbed (and "carbon (VI) oxide" does not exist anyway). Wrong.
  • E: Nitrogen is not absorbed, so it remains too. Wrong.

**Answer: B.

Exam tip: Remember the absorbers: alkaline pyrogallol → oxygen, lime water or KOH → CO₂, anhydrous CaCl₂ or conc. H₂SO₄ → water vapour. After removing O₂, CO₂ and water, what is left is nitrogen plus the noble gases.

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