NECO 2008 Chemistry · Question 26

The reaction of hydrochloric acid and calcium trioxocarbonate (IV) produces

Options

  1. A.calcium chloride, carbon (IV) oxide and water
  2. B.calcium chloride, and trioxocarbonate (IV) acid
  3. C.calcium hydroxide, carbon (IV) oxide and chlorine gas
  4. D.calcium hydroxide, carbon (IV) oxide and water
  5. E.calcium metal and water.

Answer: A. calcium chloride, carbon (IV) oxide and water

Explanation written with AI and checked against the answer key

Step 1: Analyze the question We need the products when hydrochloric acid (HCl) reacts with calcium trioxocarbonate (IV), which is calcium carbonate (CaCO₃), a carbonate.

Step 2: The concept Acids react with carbonates to form a salt + carbon (IV) oxide + water.

This happens because the carbonic acid (trioxocarbonate (IV) acid, H₂CO₃) formed in the first step is unstable. It breaks down immediately into CO₂ and H₂O.

Step 3: Solution

Step (i): Double displacement CaCO₃ + 2HCl → CaCl₂ + H₂CO₃

Step (ii): Decomposition of the unstable acid H₂CO₃ → H₂O + CO₂

Overall equation: CaCO₃(s) + 2HCl(aq) → CaCl₂(aq) + H₂O(l) + CO₂(g)

Step 4: Check the options

  • A. Calcium chloride, CO₂ and water: matches the overall equation.
  • B. Carbonic acid is unstable and does not remain as a product.
  • C. No calcium hydroxide or chlorine gas is formed.
  • D. The salt formed is CaCl₂, not Ca(OH)₂.
  • E. Calcium metal is never produced in a simple acid-carbonate reaction.

Answer: A

Exam tip: Remember "Acid + Carbonate → Salt + Water + CO₂". The fizzing (effervescence) you see in the lab is CO₂ escaping. It turns lime water milky, which is the standard test for CO₂.

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