NECO 2001 Chemistry · Question 12

Which compound is a product of the hydrolysis of the of CH3_3COOC3_3H7_7 with aqueous sodium hydroxide?

Options

  1. A.CH3COONa
  2. B.CH3COONaCCH3OH
  3. C.CH3OH
  4. D.C2H5OH
  5. E.C3H7COONa

Answer: A. CH3COONa

Explanation written with AI and checked against the answer key

Analyze the question: CH₃COOC₃H₇ is an ester (propyl ethanoate). Hydrolysis with aqueous NaOH is called saponification (alkaline hydrolysis). We need to identify a product.

Concept: An ester is made of two parts:

  • The acid part (from ethanoic acid): CH₃COO–
  • The alcohol part (from propanol): –C₃H₇

In alkaline hydrolysis, the ester reacts with NaOH to give the sodium salt of the carboxylic acid plus the alcohol:

RCOOR' + NaOH → RCOONa + R'OH

Solution:

CH₃COOC₃H₇ + NaOH → CH₃COONa + C₃H₇OH

The products are:

  • Sodium ethanoate (CH₃COONa)
  • Propan-1-ol (C₃H₇OH)

Checking the options:

  • A. CH₃COONa: correct, it is sodium ethanoate.
  • B. CH₃COONaCCH₃OH: not a real compound, just a garbled formula.
  • C. CH₃OH: methanol, which would come from a methyl ester.
  • D. C₂H₅OH: ethanol, which would come from an ethyl ester.
  • E. C₃H₇COONa: sodium butanoate, which would need a butanoic acid ester.

Only A matches a product of this reaction. The other product, propanol, is not listed among the options.

Tip: In saponification, the acid part becomes the sodium salt and the alkyl group becomes the alcohol. Match the carbons: the part with C=O (CH₃COO–) gives the salt, and the part after the oxygen (C₃H₇) gives the alcohol.

AI can make mistakes. Report anything that looks wrong.

Past questions © the examination body (JAMB/WAEC/NECO). DeeepSolve is not affiliated with them. Rights holders: see /copyright.