NECO 2001 Chemistry · Question 12
Which compound is a product of the hydrolysis of the of CHCOOCH with aqueous sodium hydroxide?
Options
- A.CH3COONa
- B.CH3COONaCCH3OH
- C.CH3OH
- D.C2H5OH
- E.C3H7COONa
Answer: A. CH3COONa
Explanation written with AI and checked against the answer key
Analyze the question: CH₃COOC₃H₇ is an ester (propyl ethanoate). Hydrolysis with aqueous NaOH is called saponification (alkaline hydrolysis). We need to identify a product.
Concept: An ester is made of two parts:
- The acid part (from ethanoic acid): CH₃COO–
- The alcohol part (from propanol): –C₃H₇
In alkaline hydrolysis, the ester reacts with NaOH to give the sodium salt of the carboxylic acid plus the alcohol:
RCOOR' + NaOH → RCOONa + R'OH
Solution:
CH₃COOC₃H₇ + NaOH → CH₃COONa + C₃H₇OH
The products are:
- Sodium ethanoate (CH₃COONa)
- Propan-1-ol (C₃H₇OH)
Checking the options:
- A. CH₃COONa: correct, it is sodium ethanoate.
- B. CH₃COONaCCH₃OH: not a real compound, just a garbled formula.
- C. CH₃OH: methanol, which would come from a methyl ester.
- D. C₂H₅OH: ethanol, which would come from an ethyl ester.
- E. C₃H₇COONa: sodium butanoate, which would need a butanoic acid ester.
Only A matches a product of this reaction. The other product, propanol, is not listed among the options.
Tip: In saponification, the acid part becomes the sodium salt and the alkyl group becomes the alcohol. Match the carbons: the part with C=O (CH₃COO–) gives the salt, and the part after the oxygen (C₃H₇) gives the alcohol.
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