NECO 2001 Chemistry · Question 16
The green colour solution of an Fe2 salt changes to a brown solution of an Fe3+ salt by
Options
- A.conversion.
- B.elimination.
- C.oxidation.
- D.reduction.
- E.substitution.
Answer: C. oxidation.
Explanation written with AI and checked against the answer key
Analyze the question: Fe²⁺ (green) changes to Fe³⁺ (brown). We need the name of this process.
Concept: Oxidation and reduction can be defined in terms of electron transfer.
- Oxidation = loss of electrons (increase in oxidation number)
- Reduction = gain of electrons (decrease in oxidation number)
Solution:
Fe²⁺ → Fe³⁺ + e⁻
- The iron loses one electron.
- Its oxidation number increases from +2 to +3.
- Loss of electrons means the iron(II) ion is oxidized.
This is why a green iron(II) solution, such as FeSO₄, turns brown or yellow-brown when exposed to air or when treated with oxidizing agents such as acidified KMnO₄, H₂O₂ or chlorine water.
The other options do not fit:
- Reduction (D) would be the reverse, Fe³⁺ → Fe²⁺.
- Conversion, elimination and substitution are not the standard terms for electron transfer in redox chemistry.
The correct answer is C. oxidation.
Exam tip: Remember OIL RIG: Oxidation Is Loss of electrons, Reduction Is Gain. Also remember the colours: Fe²⁺ is green and Fe³⁺ is brown or yellow-brown. These are often tested, including in the brown ring test and in hydroxide precipitates (green Fe(OH)₂ and reddish-brown Fe(OH)₃).
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