JAMB 2024 Chemistry · Question 71

The volume occupied by 1 mole of an ideal gas at a temperature of 130^0C and a pressure of 1.58 atm is  [ R = 0.082 atm dm3^3 K−1^{-1}mol−1^{-1} ]

Options

  1. A.14.84 dm3^3
  2. B.14.84 cm3^3
  3. C.0.64 dm3^3
  4. D.0.64 cm3^3

Answer: A. 14.84 dm3^3

Explanation written with AI and checked against the answer key

To solve this problem, we use the Ideal Gas Law equation, which relates pressure, volume, temperature, and the number of moles of a gas.

1. Analyze the Question
  • Number of moles (nn) = 1 mol
  • Temperature (TT) = 13°C
  • Pressure (PP) = 1.58 atm
  • Gas constant (RR) = 0.082 atm dm3^3 K−1^{-1}mol−1^{-1}
  • We need to find the Volume (VV).
2. Explain the Concept

The Ideal Gas Law is expressed as:

PV=nRTPV = nRT

Before we plug in the values, we must ensure the temperature is in Kelvin (K), as the gas constant RR uses Kelvin.

  • T(K)=T(°C)+273T(K) = T(°C) + 273
  • T=13+273=286 KT = 13 + 273 = 286 \text{ K}
3. Show the Solution

Rearrange the formula to solve for VV:

V=nRTPV = \frac{nRT}{P}

Substitute the given values into the equation:

V=1 mol×0.082 atm dm3 K−1mol−1×286 K1.58 atmV = \frac{1 \text{ mol} \times 0.082 \text{ atm dm}^3 \text{ K}^{-1} \text{mol}^{-1} \times 286 \text{ K}}{1.58 \text{ atm}}

Calculate the numerator:

0.082×286=23.4520.082 \times 286 = 23.452

Now, divide by the pressure (1.581.58):

V=23.4521.58V = \frac{23.452}{1.58}
V≈14.843 dm3V \approx 14.843 \text{ dm}^3

Rounding to two decimal places, we get 14.84 dm3^3.

4. Identify the Answer

Comparing our result to the given options, the correct value is 14.84 dm3^3. This matches option A.

5. Exam Tip

Always check your units before calculating! In JAMB Chemistry, a very common trap is forgetting to convert Celsius to Kelvin. If you had used 13 directly in the formula, your answer would have been completely wrong. Always add 273 to your Celsius temperature first.

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