JAMB 2024 Chemistry · Question 103
Scandium is not regarded as a transition metal because its ion has
Options
- A.no electron in the d-orbital
- B.a partially filled d-orbitals
- C.a completely filled 4S orbital
- D.a partially filled 4S orbital
Answer: A. no electron in the d-orbital
Explanation written with AI and checked against the answer key
1. Analyze the Question
The question asks why Scandium (Sc) is excluded from the strict definition of a transition metal, specifically focusing on the electronic configuration of its ion.
2. Explain the Concept
In chemistry, a transition metal is defined as an element that has an incomplete (partially filled) d-subshell in its neutral state or in at least one of its common oxidation states.
- Scandium (Sc) has an atomic number of 21.
- Its electronic configuration is: .
- When Scandium forms an ion, it loses its three outermost electrons (two from the orbital and one from the orbital) to achieve a stable noble gas configuration ().
- The configuration of the ion is: .
3. Show the Solution
- Step 1: Look at the ion configuration. You will notice that the subshell is now completely empty ().
- Step 2: Compare this to the definition of a transition metal. Since the ion has no electrons in the d-orbital, it does not meet the criteria of having a "partially filled d-orbital" in its stable ionic state.
- Step 3: Evaluate the options. • Option A: "no electron in the d-orbital" matches our finding (). • Option B: "a partially filled d-orbitals" is incorrect because the ion has zero electrons in the d-orbital. • Option C & D: These refer to the orbital, which is not the defining factor for transition metal classification (the d-orbital is).
4. Identify the Answer
5. Exam Tip
Memory Trick: Remember the "d-orbital rule." Think of transition metals as elements that have "d-electrons to spare." If an element (like Scandium or Zinc) loses its d-electrons to become stable, it loses its "transition metal" status in that specific ionic form.
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