JAMB 2024 Chemistry · Question 103

Scandium is not regarded as a transition metal because its ion has

Options

  1. A.no electron in the d-orbital
  2. B.a partially filled d-orbitals
  3. C.a completely filled 4S orbital
  4. D.a partially filled 4S orbital

Answer: A. no electron in the d-orbital

Explanation written with AI and checked against the answer key

1. Analyze the Question

The question asks why Scandium (Sc) is excluded from the strict definition of a transition metal, specifically focusing on the electronic configuration of its ion.

2. Explain the Concept

In chemistry, a transition metal is defined as an element that has an incomplete (partially filled) d-subshell in its neutral state or in at least one of its common oxidation states.

  • Scandium (Sc) has an atomic number of 21.
  • Its electronic configuration is: 1s22s22p63s23p64s23d11s^2 2s^2 2p^6 3s^2 3p^6 4s^2 3d^1.
  • When Scandium forms an ion, it loses its three outermost electrons (two from the 4s4s orbital and one from the 3d3d orbital) to achieve a stable noble gas configuration (Sc3+Sc^{3+}).
  • The configuration of the Sc3+Sc^{3+} ion is: 1s22s22p63s23p61s^2 2s^2 2p^6 3s^2 3p^6.
3. Show the Solution
  • Step 1: Look at the Sc3+Sc^{3+} ion configuration. You will notice that the 3d3d subshell is now completely empty (3d03d^0).
  • Step 2: Compare this to the definition of a transition metal. Since the Sc3+Sc^{3+} ion has no electrons in the d-orbital, it does not meet the criteria of having a "partially filled d-orbital" in its stable ionic state.
  • Step 3: Evaluate the options. • Option A: "no electron in the d-orbital" matches our finding (3d03d^0). • Option B: "a partially filled d-orbitals" is incorrect because the ion has zero electrons in the d-orbital. • Option C & D: These refer to the 4s4s orbital, which is not the defining factor for transition metal classification (the d-orbital is).
4. Identify the Answer
5. Exam Tip

Memory Trick: Remember the "d-orbital rule." Think of transition metals as elements that have "d-electrons to spare." If an element (like Scandium or Zinc) loses its d-electrons to become stable, it loses its "transition metal" status in that specific ionic form.

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