JAMB 2023 Chemistry · Question 23

What is the IUPAC name for the compound CCl4_4?

Options

  1. A.Tetrahydrochloride
  2. B.Tetrachloromethane
  3. C.Carbon tetrachloride
  4. D.Chloroform

Answer: B. Tetrachloromethane

Explanation written with AI and checked against the answer key

Step 1: Analyze the question The question asks for the IUPAC (systematic) name of CCl₄, not its common or trivial name. That distinction decides the answer.

Step 2: The concept In IUPAC nomenclature for simple halogenoalkanes:

  • Find the parent alkane. Here there is one carbon, so the parent is methane.
  • Name the halogen substituents as prefixes (chloro-, bromo-, and so on).
  • Use multiplying prefixes (di-, tri-, tetra-) to show how many of each substituent there are.

Step 3: Solution

  • Parent chain: 1 carbon → methane
  • Substituents: 4 chlorine atoms → tetrachloro
  • Full name: tetrachloromethane

Step 4: Check the other options

  • A. Tetrahydrochloride: not a valid name for this compound.
  • C. Carbon tetrachloride: this is the common (trivial) name, widely used but not the IUPAC name.
  • D. Chloroform: this is the common name for CHCl₃ (trichloromethane), a different compound.

Answer: B. Tetrachloromethane

Exam tip: When a question says "IUPAC name", look for the systematic name built from the alkane parent plus prefixes. Remember these pairs:

  • CHCl₃: chloroform, IUPAC name trichloromethane
  • CCl₄: carbon tetrachloride, IUPAC name tetrachloromethane

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