JAMB 2023 Chemistry · Question 53

Chlorine gas is commonly used in the production of which of the following industrial compounds?

Options

  1. A.Chlorofluorocarbons (CFCs)
  2. B.Methane
  3. C.Ammonia
  4. D.Ethanol

Answer: A. Chlorofluorocarbons (CFCs)

Explanation written with AI and checked against the answer key

Analysis of the Question

The question asks for an industrial compound that requires chlorine gas as a raw material for its production. We need to evaluate each option based on industrial chemical processes.

Explanation of Concepts
  • Chlorine Gas (Cl2Cl_2): A highly reactive halogen used extensively in the chemical industry for bleaching, water treatment, and the synthesis of organic and inorganic compounds.
  • Chlorofluorocarbons (CFCs): These are organic compounds that contain carbon, chlorine, and fluorine. They are produced by replacing the hydrogen atoms in hydrocarbons (like methane or ethane) with chlorine and fluorine atoms through a process called halogenation. Chlorine gas is a primary reagent in this process.
  • Methane (CH4CH_4): This is a naturally occurring hydrocarbon (the main component of natural gas). It is a raw material, not a product made from chlorine.
  • Ammonia (NH3NH_3): Produced industrially via the Haber Process, which involves the reaction of nitrogen gas (N2N_2) and hydrogen gas (H2H_2). Chlorine is not involved.
  • Ethanol (C2H5OHC_2H_5OH): Produced industrially by the hydration of ethene or the fermentation of sugars. Chlorine is not a reactant in these processes.
Step-by-Step Solution
  1. Evaluate Option A: CFCs (e.g., CCl2F2CCl_2F_2) are synthesized by reacting hydrocarbons with chlorine and fluorine. Chlorine gas is essential for the chlorination step.
  2. Evaluate Option B: Methane is a starting material (a reactant), not a product of a process using chlorine.
  3. Evaluate Option C: Ammonia is synthesized from Nitrogen and Hydrogen. Chlorine is not part of the Haber process.
  4. Evaluate Option D: Ethanol is produced from ethene or glucose. Chlorine is not used in these production pathways.

Since chlorine is a fundamental component in the synthesis of CFCs, Option A is the correct industrial application.

Conclusion

The production of Chlorofluorocarbons (CFCs) relies on the substitution of hydrogen atoms in alkanes with chlorine atoms, making chlorine gas a vital industrial input for this process.

Exam Tip

When you see questions about industrial chemistry, remember the "Haber-Contact-Solvay" trio:

  • Haber Process: Ammonia (NH3NH_3)
  • Contact Process: Sulfuric Acid (H2SO4H_2SO_4)
  • Solvay Process: Sodium Carbonate (Na2CO3Na_2CO_3) If the question asks about chlorine, look for keywords like "bleaching," "PVC," or "CFCs."

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