JAMB 2022 Chemistry · Question 8

If the volume of a given mass of a gas at 0ºc is 29.5cm3^3. What will be the volume of the gas at 15ºc, given that the pressure remains constant.

Options

  1. A.31.6
  2. B.62.2
  3. C.32.7
  4. D.31.1

Answer: D. 31.1

Explanation written with AI and checked against the answer key

1. Analyze the question

We are given the initial volume (V1V_1) and initial temperature (T1T_1) of a gas. We need to find the new volume (V2V_2) at a new temperature (T2T_2), while the pressure remains constant. This is a classic application of Charles's Law.

2. Explain the concept

Charles's Law states that for a fixed mass of gas at constant pressure, the volume is directly proportional to its absolute temperature (measured in Kelvin).

The formula is:

V1T1=V2T2\frac{V_1}{T_1} = \frac{V_2}{T_2}

Important Note: In gas law calculations, temperatures must always be converted from Celsius (°C) to Kelvin (K) by adding 273.15 (or simply 273 for most JAMB calculations).

3. Show the solution

Step 1: List the given values

  • V1=29.5 cm3V_1 = 29.5 \text{ cm}^3
  • T1=0∘C=0+273=273 KT_1 = 0^\circ\text{C} = 0 + 273 = 273 \text{ K}
  • T2=15∘C=15+273=288 KT_2 = 15^\circ\text{C} = 15 + 273 = 288 \text{ K}
  • V2=?V_2 = ?

Step 2: Rearrange the formula to solve for V2V_2

V2=V1×T2T1V_2 = \frac{V_1 \times T_2}{T_1}

Step 3: Substitute the values into the equation

V2=29.5×288273V_2 = \frac{29.5 \times 288}{273}

Step 4: Calculate the result

V2=8496273V_2 = \frac{8496}{273}
V2≈31.12 cm3V_2 \approx 31.12 \text{ cm}^3

Rounding to one decimal place, we get 31.1 cm³.

4. Identify the answer

Comparing our result to the given options, the correct choice is D.

5. Tip

Always remember the "Kelvin Rule": If you forget to convert Celsius to Kelvin in a gas law problem, you will almost certainly get the wrong answer. A quick way to check your work is to see if the volume changed in the same direction as the temperature—since the temperature increased, the volume must also increase.

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