JAMB 2019 Chemistry · Question 78

Which of the following describes the chemical property of acids?

Options

  1. A.None of the above
  2. B.Acid + XCO3_3 →\to Salt + H2_2O + NH3_3
  3. C.Acid + NaOH →\to Normal salt + CO2_2
  4. D.Acid + Xn_nCO3_3 →\to Salt + H2_2O + CO2_2

Answer: D. Acid + Xn_nCO3_3 →\to Salt + H2_2O + CO2_2

Explanation written with AI and checked against the answer key

Analysis of the Question

The question asks for the general chemical property of acids when they react with carbonates. In chemistry, acids undergo specific neutralization and displacement reactions. We need to identify the correct balanced chemical equation that represents the reaction between an acid and a metal carbonate.

Concept Explanation

When an acid reacts with a metal carbonate (represented here as XnCO3X_nCO_3, where XX is a metal), the reaction follows a standard pattern: Acid + Metal Carbonate →\to Salt + Water + Carbon(IV) oxide

  • Acid: Provides the hydrogen ions (H+H^+).
  • Metal Carbonate: Provides the carbonate ion (CO32−CO_3^{2-}).
  • Products: The metal from the carbonate combines with the anion of the acid to form a salt. The hydrogen from the acid combines with the oxygen from the carbonate to form water (H2OH_2O), and the remaining carbon and oxygen form carbon(IV) oxide (CO2CO_2).
Step-by-Step Solution

Let’s evaluate the options provided:

  • Option B: Acid+XCO3→Salt+H2O+NH3Acid + XCO_3 \to Salt + H_2O + NH_3. This is incorrect because the reaction between an acid and a carbonate produces CO2CO_2, not ammonia (NH3NH_3).
  • Option C: Acid+NaOH→Normalsalt+CO2Acid + NaOH \to Normal salt + CO_2. This is incorrect because NaOHNaOH is a base (alkali), not a carbonate. The reaction between an acid and a base (neutralization) produces only salt and water (Acid+Base→Salt+WaterAcid + Base \to Salt + Water).
  • Option D: Acid+XnCO3→Salt+H2O+CO2Acid + X_nCO_3 \to Salt + H_2O + CO_2. This perfectly matches the general chemical principle described above. The "nn" in XnCO3X_nCO_3 represents the valency of the metal XX, which is standard notation for chemical formulas.
Conclusion

The reaction between an acid and a metal carbonate consistently yields a salt, water, and carbon(IV) oxide. Option D is the only equation that correctly represents these products.

Exam Tip: Whenever you see a reaction involving a carbonate (CO3CO_3) and an acid, always look for CO2CO_2 in the products. If you see NH3NH_3 or other gases, you can immediately rule those options out!

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