JAMB 2019 Chemistry · Question 19

When ammonia and hydrogen ion bond together to form ammonium ion, the bond formed is called

Options

  1. A.electrovalent bond
  2. B.compound bond
  3. C.ionic bond
  4. D.covalent bond

Answer: D. covalent bond

Explanation written with AI and checked against the answer key

Analyze the question: NH₃ + H⁺ → NH₄⁺. We need to name the type of bond that forms between the ammonia molecule and the hydrogen ion.

Explain the concept:

  • In NH₃, nitrogen has a lone pair of electrons (it uses 3 of its 5 valence electrons to bond with 3 hydrogens).
  • The H⁺ ion has no electrons (an empty 1s orbital).
  • Nitrogen donates its lone pair to H⁺, and the two atoms share that pair of electrons.
  • A bond formed by sharing electrons is a covalent bond. Because both shared electrons come from one atom (nitrogen), it is a special type called a dative (coordinate) covalent bond.

Step-by-step solution:

  1. NH₃ has the structure H–N–H with H below, and a lone pair on N.
  2. H⁺ approaches the lone pair.
  3. N donates the lone pair → N–H bond forms.
  4. Once formed, all four N–H bonds in NH₄⁺ are identical. You cannot tell which one was the dative bond.

Checking the options:

  • A. Electrovalent bond: this means ionic (transfer of electrons). It is not correct, because no electron is transferred.
  • B. Compound bond: not a recognized type of chemical bond.
  • C. Ionic bond: the same as electrovalent, so it is incorrect.
  • D. Covalent bond: correct. It is the dative or coordinate covalent bond, a type of covalent bond.

The NH₄⁺ ion as a whole carries a charge and forms ionic compounds (such as NH₄Cl) with other ions, but the bond within the ion, between N and H, is covalent.

Answer: D, covalent bond (specifically a dative/coordinate covalent bond).

Exam tip: Whenever you see NH₄⁺, H₃O⁺, or the formation of complexes, think "lone pair donated to an empty orbital", which is a coordinate (dative) covalent bond. Remember: dative = both electrons from one atom, but still covalent.

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