JAMB 2019 Chemistry · Question 54

The hybridization in the compound CH3−CH2−C≡HCH_3 - CH_2 - C \equiv H is

Options

  1. A.sp3^3 and sp
  2. B.sp
  3. C.sp2^2
  4. D.sp3^3 and sp2^2

Answer: A. sp3^3 and sp

Explanation written with AI and checked against the answer key

To solve this problem, we need to look at the bonding around each carbon atom in the molecule.

Note: There appears to be a slight typo in your question. The structure CH3−CH2−C≡HCH_3 - CH_2 - C \equiv H is chemically impossible because carbon must form four bonds. The correct structure for this series is CH3−CH2−C≡CHCH_3 - CH_2 - C \equiv CH (butyne).

1. Analyze the concept: Hybridization

Hybridization is determined by the number of sigma (σ\sigma) bonds and lone pairs around a central atom:

  • sp3sp^3 hybridization: Occurs when a carbon atom is bonded to 4 other atoms (single bonds only).
  • sp2sp^2 hybridization: Occurs when a carbon atom is bonded to 3 other atoms (one double bond).
  • spsp hybridization: Occurs when a carbon atom is bonded to 2 other atoms (one triple bond or two double bonds).
2. Step-by-step breakdown

Let's analyze the structure CH3−CH2−C≡CHCH_3 - CH_2 - C \equiv CH:

  • Carbon 1 (CH3CH_3): This carbon is bonded to 3 hydrogens and 1 carbon (all single bonds). Since it has 4 sigma bonds, it is sp3sp^3 hybridized.
  • Carbon 2 (CH2CH_2): This carbon is bonded to 2 hydrogens and 2 carbons (all single bonds). Since it has 4 sigma bonds, it is sp3sp^3 hybridized.
  • Carbon 3 (−C≡-C \equiv): This carbon is bonded to one carbon on the left and one carbon on the right via a triple bond. It is bonded to only 2 atoms. Therefore, it is spsp hybridized.
  • Carbon 4 (≡CH\equiv CH): This carbon is bonded to one carbon and one hydrogen. It is bonded to only 2 atoms. Therefore, it is spsp hybridized.
3. Conclusion

The molecule contains carbon atoms that are either sp3sp^3 hybridized or spsp hybridized. Looking at the options provided, the combination present in the chain is sp3sp^3 and spsp.

Option A is the best fit among the choices provided.

Exam Tip: Always count the number of atoms attached to the carbon. If it's 4 atoms, it's sp3sp^3; if it's 3, it's sp2sp^2; if it's 2, it's spsp. Ignore the pi bonds (the second and third lines in double/triple bonds) when counting for hybridization!

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