JAMB 2019 Chemistry · Question 6

Methane is prepared in the laboratory by heating a mixture of sodium ethanoate with soda lime. The chemical constituent(s) of soda lime is/are

Options

  1. A.Ca(OH)2_2 and NaOH
  2. B.Na2_2CO3_3
  3. C.NaCl
  4. D.NaOH

Answer: A. Ca(OH)2_2 and NaOH

Explanation written with AI and checked against the answer key

Analysis

The question asks for the chemical composition of soda lime, which is a reagent used in the laboratory preparation of methane (an alkane) through a process called decarboxylation.

Concept Explanation

In organic chemistry, the preparation of methane from sodium ethanoate (CH3COONaCH_3COONa) involves heating the salt with soda lime. The reaction is represented by the following equation:

CH3COONa+NaOH→CaO,ΔCH4(g)+Na2CO3(s)CH_3COONa + NaOH \xrightarrow{CaO, \Delta} CH_4(g) + Na_2CO_3(s)
  • Soda lime is not a single chemical compound but a mixture.
  • Sodium hydroxide (NaOHNaOH) is the active reagent that provides the hydroxide ion to remove the carboxyl group (–COONa–COONa) from the sodium ethanoate.
  • Calcium hydroxide (Ca(OH)2Ca(OH)_2) is added to the mixture to keep the sodium hydroxide in a solid, granular form and to prevent it from being too deliquescent (absorbing moisture from the air and turning into a liquid). It also helps to moderate the reaction.
Step-by-Step Solution
  1. Identify the components: Soda lime is a mixture of two main substances: Sodium hydroxide (NaOHNaOH) and Calcium hydroxide (Ca(OH)2Ca(OH)_2).
  2. Evaluate the options: • Option A lists both Ca(OH)2Ca(OH)_2 and NaOHNaOH, which matches the definition of soda lime. • Option B (Na2CO3Na_2CO_3) is a product of the reaction, not the reagent. • Option C (NaClNaCl) is common table salt and is not involved in this reaction. • Option D (NaOHNaOH) is only one part of the mixture; soda lime specifically refers to the combination of NaOHNaOH and Ca(OH)2Ca(OH)_2.
Conclusion

The chemical constituents of soda lime are indeed a mixture of sodium hydroxide and calcium hydroxide.

Exam Tip: Remember that "soda" refers to the sodium hydroxide (NaOHNaOH) and "lime" refers to the calcium hydroxide (Ca(OH)2Ca(OH)_2). This mnemonic will help you identify the mixture easily in future exams.

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