JAMB 2018 Chemistry · Question 26
Diamond is a bad conductor of electricity because its bonding electrons are used in
Options
- A.crystal lattice formation
- B.covalent bond formation
- C.metallic bond formation
- D.coordinate bond formation
Answer: B. covalent bond formation
Explanation written with AI and checked against the answer key
Step 1: Analyze the question We are asked why diamond does not conduct electricity. The key is to ask what its bonding electrons are doing.
Step 2: Explain the concept Electrical conductivity needs mobile charge carriers, meaning free electrons or free ions.
- Metals conduct because they have delocalised electrons that move freely (metallic bonding).
- Graphite conducts because each carbon uses only 3 of its 4 outer electrons in bonding, leaving one delocalised electron per atom.
- Diamond is different. Each carbon atom uses all 4 of its outer electrons to form 4 strong covalent bonds with 4 other carbon atoms in a rigid tetrahedral arrangement.
Step 3: Apply to diamond Because all the valence electrons are held in localised covalent bonds, there are no free electrons and no ions. No charge carriers can move, so diamond is a poor conductor (an insulator).
Step 4: Check the options
- A. Crystal lattice formation: diamond does have a giant lattice, but a lattice is the structure, not the type of bonding that uses up the electrons. Metals also have lattices and they conduct.
- B. Covalent bond formation: correct. The electrons are all tied up in covalent bonds.
- C. Metallic bond formation: wrong, since diamond has no metallic bonding.
- D. Coordinate bond formation: wrong, since diamond's bonds are normal shared-pair covalent bonds, not dative bonds.
Answer: B. Covalent bond formation
Exam tip: Remember "Diamond: 4 bonds, 0 free electrons → no conduction. Graphite: 3 bonds, 1 free electron → conducts." Questions comparing diamond and graphite appear often in JAMB.
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