JAMB 2017 Chemistry · Question 2

The ideal gas laws and equations are true for all gases at

Options

  1. A.low pressures and lower temperatures
  2. B.low temperatures and high pressures
  3. C.high pressures and high temperatures
  4. D.low pressure and high temperatures

Answer: D. low pressure and high temperatures

Explanation written with AI and checked against the answer key

Analysis

The question asks for the specific conditions under which real gases behave most like an "ideal gas." In chemistry, we assume ideal gas behavior to simplify calculations using the Ideal Gas Equation (PV=nRTPV = nRT).

Concept Explanation

Real gases deviate from ideal behavior because:

  1. Molecular Volume: Real gas molecules occupy space, whereas ideal gas particles are considered point masses with negligible volume.
  2. Intermolecular Forces: Real gas molecules exert attractive forces on each other (Van der Waals forces), whereas ideal gas particles are assumed to have no such interactions.

To make a real gas behave like an ideal gas, we must minimize these two factors:

  • High Temperature: At high temperatures, gas particles have high kinetic energy. This energy allows them to overcome the weak intermolecular attractive forces.
  • Low Pressure: At low pressures, the gas particles are spread far apart. This makes the volume of the individual gas molecules negligible compared to the large empty space between them.
Step-by-Step Solution
  1. Evaluate the conditions: • If pressure is high, particles are crowded together, making the volume of the molecules significant and increasing the frequency of collisions/interactions. This leads to deviation from ideal behavior. • If temperature is low, particles move slowly, allowing intermolecular forces to pull them together, which also leads to deviation.
  2. Identify the ideal conditions: • To minimize interactions, we need low pressure (to increase distance between particles). • To minimize the effect of intermolecular forces, we need high temperature (to increase kinetic energy).
  3. Match with options: Comparing our findings with the given options, the condition "low pressure and high temperatures" is the correct physical state for ideal gas behavior.
Conclusion

Exam Tip: Remember the mnemonic "High T, Low P" for Ideal Gases. Think of it as "High Temperature gives them the energy to ignore each other, and Low Pressure gives them the space to ignore each other."

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