JAMB 2016 Chemistry · Question 39

Alkanols have the general molecular formula

Options

  1. A.CnH2n-2
  2. B.CnH2n+1CHO
  3. C.CnH2n-2OH
  4. D.CnH2n+1OH

Answer: D. CnH2n+1OH

Explanation written with AI and checked against the answer key

Analyze the question: You are asked for the general molecular formula of alkanols (alcohols).

Explain the concept: Alkanols are derived from alkanes by replacing one hydrogen atom with a hydroxyl (-OH) group.

  • Alkanes have the general formula CnH2n+2.
  • Remove one H to get the alkyl group: CnH2n+1.
  • Attach the -OH group: CnH2n+1OH.

Check with examples:

  • n = 1: CH3OH (methanol)
  • n = 2: C2H5OH (ethanol)
  • n = 3: C3H7OH (propanol)

All of these fit CnH2n+1OH.

Check the other options:

  • A. CnH2n-2 is the general formula for alkynes, not alkanols.
  • B. CnH2n+1CHO is the formula for alkanals (aldehydes), such as CH3CHO (ethanal).
  • C. CnH2n-2OH does not match any standard homologous series of alcohols.
  • D. CnH2n+1OH is the correct formula for alkanols.

Tip: Remember the pattern of suffixes and formulas:

  • Alkane (-ane): CnH2n+2
  • Alkene (-ene): CnH2n
  • Alkyne (-yne): CnH2n-2
  • Alkanol (-ol): CnH2n+1OH
  • Alkanal (-al): CnH2n+1CHO

"-ol" means the -OH group, so look for the formula ending in OH with the alkyl part CnH2n+1.

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